Order of Photocatalytic Degradation as Ranked by Critical Photonic Times (CPTs) Indicates the Composition of Organic Dye Mixtures: Selectivity of Hydroxyl Radicals

Abstract

A simple critical photonic time (CPT) ranking method for the simultaneous determination of known organic dyes in the industrial wastewater of different concentrations was developed. A kinetic-measure, CPT theory, was developed to discriminate between the dyes in the textile effluent solution. The CPTs were calculated and ranked 1-4 from the smallest to the largest. The ranks indicate the order in which the individual dyes in the effluents were photocatalytically degraded. The described procedure allowed us to monitor the decolorization kinetics of the dyes in mixtures of different concentrations, when subjected to immobilized TiO2 photocatalysis in the presence of H2O2 from the start (H2O2FS). The outcome of hydroxyl radical (HO*) attack was consistently specific and regioselective for the individual dyes in the textile effluent. To explain the effect of HO*, the order of degradation of Acid Orange 52 < Acid Yellow 36 < Acid Red 17 < Acid Blue 45 < polyvinyl alcohol (PVA) was inferred.

The solid–solid interface: Explaining the high and unique photocatalytic reactivity of TiO2-based nanocomposite materials

“…Selectivity is even more crucial in other processes such as the partial oxidation of hydrocarbons and NOx decomposition [156,157]. There are a few studies in the literature concerning factors that influence the selectivity in photocatalytic processes, including wavelength of light [156,158], acidity [159], temperature [160], reactants [161,162], and surface characteristics of photocatalysts [163].…”