Adsorption heat conversion systems can provide heating
and cooling
across time and space in a more environmentally friendly way. Porous
materials are potential candidates for water-based adsorption thermal
conversion, in which a metal–organic framework (MOF) has a
larger specific surface area and porosity than other porous matrices.
However, many MOFs with high saturated adsorption capacity have great
deficiencies in performance at low water vapor partial pressure, which
hinder their application in adsorption thermal conversion. To improve
the water vapor adsorption performance of MIL-101 (Cr), different
contents of magnesium chloride, lithium chloride, and lanthanum chloride
are mixed into MIL-101 (Cr) by an impregnation method. The properties
and structures of the materials are characterized by XRD, SEM, nitrogen
adsorption tests, water vapor adsorption tests, TG, FTIR, and so on.
The results show that the saturated water vapor adsorption capacity
of the sample impregnated with salt increases by 1.5–2.3 times,
up to 2.24 g/g, compared with that of the unimpregnated sample. When
the partial pressure of water vapor is 0.3, the adsorption capacity
increases by 5.3–7.5 times and reaches 0.68 g/g at most. The
maximum heat storage density of impregnated samples can be increased
by 866 J/g. Impregnated MgCl2 can greatly improve the adsorption
and thermal conversion performance of MOF, and impregnated MgCl2 and the proper amount of LiCl can further improve the performance
of the material system. Our experiments show that the composite impregnation
of magnesium chloride and the proper amount of lithium chloride can
improve the application performance of the MOF materials in the adsorption
thermal conversion process.