Reverse electrodialysis in closed loop configurations is a promising membrane technology in the energy conversion and storage fields. One of the main advantages of closed-loop reverse electrodialysis is the possibility of using a wide range of operating concentrations, flow rates and different salts for generating the salinity gradient. In this work, an original exergy analysis of the reverse electrodialysis process was carried out in order to investigate reverse electrodialysis performance in terms of energetic and exergetic efficiency parameters in a wide range of operating conditions. A mono-dimensional model of the reverse electrodialysis process was developed, in which all sources of irreversibility are considered, such as non-ideal membranes permselectivity, ohmic losses and uncontrolled mixing phenomena (salt and water diffusive flux across membranes). For each of them, the influence on the exergy efficiency is quantified and compared. Results also indicate how exergetic and energetic performance are largely dependent on solutions concentration: when high salinity gradient differences are used within the unit, membrane water permeability heavily affects process performance, thus reducing exergy efficiency, though a larger power output can be normally achieved. The more performing flow arrangement for the stack has been found to be the counter-current, though

Abstract:The use of renewable energy sources is one of the most relevant goals to be achieved in order to match the climate protection targets. As a case study, the paper shows the current electrical energy production by sources in the Sicilian context. Among the renewable energy sources, the paper investigates the wave energy potential along the Sicilian coasts, because of the favorable climate around the island. A point absorber is present in order to exploit this source. Two scenarios are presented, with two different levels of energy production.

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Thermoeconomic diagnosis of refrigeration systems is a pioneering approach to the diagnosis of malfunctions, which has been recently proven to achieve good performances for the detection of specific faults. Being an exergy-based diagnostic technique, its performance is influenced by the trends of exergy functions in the "design" and "abnormal" conditions. In this paper the sensitivity of performance of thermoeconomic diagnosis in detecting a fouled direct expansion coil and quantifying the additional consumption it induces is investigated; this fault is critical due to the simultaneous air cooling and dehumidification occurring in the coil, that induce variations in both the chemical and thermal fractions of air exergy. The examined parameters are the temperature and humidity of inlet air, the humidity of reference state and the sensible/latent heat ratio (varied by considering different coil depths). The exergy analysis reveals that due to the more intense dehumidification occurring in presence of fouling, the exergy efficiency of the evaporator coil eventually increases. Once the diagnostic technique is based only on the thermal fraction of air exergy, the results suggest that the performance of the technique increases when inlet air has a lower absolute humidity, as evident from the "optimal performance" regions identified on a psychrometric chart.