Optimization of parameters for portable X-ray diffraction/X-ray fluorescence combined analysis device (P-XRDF-CAD)

Abstract

This paper aims to optimize the parameters of a portable device that combines X-ray diffraction (XRD) and X-ray fluorescence (XRF) analysis techniques. By using the same X-ray source and detector, the device enables the simultaneous acquisition of two-dimensional XRD and XRF information from a sample with the advantage of high analysis efficiency and consistency in the measurement points. The equipment and slit materials are discussed, including the selection of the X-ray source (Moxtek MAGNUM) and the detector (Andor CCD camera). We also explore two different slit designs (the bottom-hole and side-hole) and optimize their dimensions using rectangular holes instead of inclined trapezoidal holes. Considering the fluorescence X-rays of the filters in the X-ray tube spectra, a theoretical formula is derived for rapid and accurate calculation. The calculated results are compared with the experimental results of Al and Ni filters, demonstrating good agreement across various tube voltages and filter thicknesses. Furthermore, an XRD/XRF comprehensive analysis platform is established. The effects of tube voltage, tube current, exposure time, and pixel-binning on the single-pixel events of the CCD camera are investigated and can be used to guide the selection of appropriate device parameters. The effects of the frame and tube voltage on the XRD/XRF analysis efficiency are examined for several sample materials, including Al, α-Fe, Zn, and ZrO2(Y2O3).