Phase equilibria in the system Nd~o3-P20S-H2o was studied under a hydrothermal cond1t1on at SOOoC under 100 MPa by a quenching technique using encapsuled samples. Equilibria among Nd phosphates; NdPS014' NdP309 and NdP04, and liquid phase could be atta1ned within 24 h. The stability fields for liquid (L), NdPS014+L, NdPS014+NdP309+L, NdP309+L, NdP309+NdP04+L, Nd~04+L and NdPo4+Nd(OH)3+H20 have been determined. The composition of the 11quid phase witP which NdPSo14 and NdP309 or NdP309 and NdPo4 could coexist was 3% Nd203-80% P20S-17% H~O or 4% Nd203-73% P20S-23% H 2 0 respectively, at SOO C under 100 MPa. A phase diagram was constructed under this condition. Crystal growth of NdPS014 were tried under the equilibrium condition. Diamond-shaped crystals 0.3 rom in size were grown at SOO°C for 4 days under 100 MPa. Crystals tended to show aggregation and surface roughness at lower growth temperatures. The crystals with polyhedral shape and maximum O.S rom in size were grown at 6S0°C.
IneroductionSince Danielmeyer and Weber(l) found an effective laser action in NdP S o14 crystal, this material has been studied extensively for laser action (2-S) , crystal structure (6-8) , ferroelectric behavior(9,10) and crystal growth (11)(12)(13)(14)(15)(16)