1997
DOI: 10.1063/1.119136
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Optical phonons in laser-deposited CdSxTe1−x films

Abstract: We report the longitudinal optical (LO) phonon frequencies for thin films of the ternary alloy CdSxTe1−x and their composition dependence for the full range of x values from pure CdTe to pure CdS. Pulsed laser deposition was used to prepare the polycrystalline thin films including compositions well inside the miscibility gap. We find that this ternary system exhibits a “two-mode” behavior with CdS- and CdTe-like longitudinal optic phonon modes. The modified random-element isodisplacement model yields a good de… Show more

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Cited by 25 publications
(13 citation statements)
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“…25,26 Through the piezo-effect ͑illustrated in Fig. 25,26 Through the piezo-effect ͑illustrated in Fig.…”
Section: A Characteristic Parametersmentioning
confidence: 99%
“…25,26 Through the piezo-effect ͑illustrated in Fig. 25,26 Through the piezo-effect ͑illustrated in Fig.…”
Section: A Characteristic Parametersmentioning
confidence: 99%
“…The most successful device structure for this material is a heterostructure with a CdS window layer. In spite of the large lattice mismatch between CdTe and CdS ($10%) [3], different crystal structure (cubic vs. hexagonal), and difference in the electron affinity, cells using CdTe prepared by a variety of low-cost techniques [4] have shown efficiencies greater than 10% and as high as 15.8% and 16.5% [5][6][7]. In view of the difficulty of forming a complete microscopic model for growth of CdTe/CdS interface, it is interesting to examine first empirically how film growth proceeds.…”
Section: Introductionmentioning
confidence: 98%
“…This is similar to the epitaxial growth of metastable alloys at low substrate temperatures to kinetically suppress thermodynamic phase separation. [92][93][94][95][96][97][98][99][100][101][102] The growth window outlined above works well provided there is a sufficiently high oxidant flux to avoid any oxidation kinetics issues. 69 At the end of the film growth, the strontium/calcium and ruthenium shutters were closed simultaneously and the samples were rapidly cooled under the same ozone pressure as that used during growth until the substrate temperature was below 250 • C.…”
mentioning
confidence: 99%