Abstract:Supported Pd/CeO2 catalytic systems have been widely investigated in the low-temperature oxidation of CO (LTO CO) due to the unique oxygen storage capacity and redox properties of the ceria support, which highly influence the structural, chemical and electronic state of Pd species. Herein, operando near-ambient pressure XPS (NAP-XPS) technique has allowed the study of a conventional Pd/CeO2 catalyst surface during the CO oxidation reaction under experimental conditions closer to the actual catalytic reaction, … Show more
“…54 Moreover, two additional peaks appeared at 534.9 and 532.5 eV suggesting the presence of PdO and C-O-Pd bonding interaction which substantially overlap with O 1s bands. 71 The XPS measurement confirms successful conversion of Pd(II) to Pd(0) and the generation of Pd NPs within the matrix of peptide bolaamphiphiles.…”
Section: Catalysis Science and Technology Papermentioning
The electrochemical cross-coupling has arisen as one of the promising greener approaches for constructing C-C bonds. The electro-organic synthesis demands a suitable electrode material capable of performing chemical transformations over...
“…54 Moreover, two additional peaks appeared at 534.9 and 532.5 eV suggesting the presence of PdO and C-O-Pd bonding interaction which substantially overlap with O 1s bands. 71 The XPS measurement confirms successful conversion of Pd(II) to Pd(0) and the generation of Pd NPs within the matrix of peptide bolaamphiphiles.…”
Section: Catalysis Science and Technology Papermentioning
The electrochemical cross-coupling has arisen as one of the promising greener approaches for constructing C-C bonds. The electro-organic synthesis demands a suitable electrode material capable of performing chemical transformations over...
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