“…The use of composite metal oxides makes possible the gas sensor suitable for particular ambience due to their sensing properties can be controlled by altering their chemical compositions [6]. Chen et al [7] obtained 3D flowerlike Zn 2 SnO 4 by a simple hydrothermal method, and the obtained Zn 2 SnO 4 exhibited superior ethanol sensing performance. An et al [8] reported that the Zn 2 SnO 4 -based sensor exhibited high response, good repeatability, and long-term stability toward ethanol gas than pure ZnO and SnO 2 sensors.…”
Highly sensitive formaldehyde chemical sensor was fabricated using uniform and mono-disperse ZnSnO 3 microspheres, which were successfully prepared by a template-free, economical in situ precipitation method combined with subsequent calcination. The orientation and morphology of the precursor, ZnSn(OH) 6 microspheres, were carefully controlled by adjusting the added amount of NaOH. This facile process may provide an approach to synthesis of functional nanomaterials with unique structures and excellent physicochemical properties. Moreover, the asfabricated sensors based on the ZnSnO 3 microspheres showed high response and short response-recovery time toward formaldehyde. To 50 ppm formaldehyde, the sensor response (S) was 17 at a working temperature of 260°C, and the response and recovery time were 6 and 18 s, respectively. The gas response of sensors based on the ZnSnO 3 microspheres was linear with the concentration of formaldehyde in the range of 5-100 ppm with a correlation coefficient of 0.997. These results showed that the as-prepared ZnSnO 3 microspheres have a potential application in gas sensor.
“…The use of composite metal oxides makes possible the gas sensor suitable for particular ambience due to their sensing properties can be controlled by altering their chemical compositions [6]. Chen et al [7] obtained 3D flowerlike Zn 2 SnO 4 by a simple hydrothermal method, and the obtained Zn 2 SnO 4 exhibited superior ethanol sensing performance. An et al [8] reported that the Zn 2 SnO 4 -based sensor exhibited high response, good repeatability, and long-term stability toward ethanol gas than pure ZnO and SnO 2 sensors.…”
Highly sensitive formaldehyde chemical sensor was fabricated using uniform and mono-disperse ZnSnO 3 microspheres, which were successfully prepared by a template-free, economical in situ precipitation method combined with subsequent calcination. The orientation and morphology of the precursor, ZnSn(OH) 6 microspheres, were carefully controlled by adjusting the added amount of NaOH. This facile process may provide an approach to synthesis of functional nanomaterials with unique structures and excellent physicochemical properties. Moreover, the asfabricated sensors based on the ZnSnO 3 microspheres showed high response and short response-recovery time toward formaldehyde. To 50 ppm formaldehyde, the sensor response (S) was 17 at a working temperature of 260°C, and the response and recovery time were 6 and 18 s, respectively. The gas response of sensors based on the ZnSnO 3 microspheres was linear with the concentration of formaldehyde in the range of 5-100 ppm with a correlation coefficient of 0.997. These results showed that the as-prepared ZnSnO 3 microspheres have a potential application in gas sensor.
“…By changing the proportion of graphene, it could be found from the response curve of Figure 17 that each material had the best response at room temperature (20 °C). Compared with the higher operating temperature (200 °C or higher) of other undoped zinc stannate materials [ 31 , 73 , 74 , 75 ], the result showed that graphene has a good improvement effect on working temperature. At the same time, it can be seen intuitively in the curve that the best response (18.9) to formaldehyde gas was when the graphene doping content is 0.5 wt%.…”
Section: Enhancingmentioning
confidence: 93%
“…The 3D flower-like structure provides an inward diffusion path for the gas, so it is capable of improving the sensing performance effectively. Chen et al [ 31 ] demonstrated the enormous gap between the Zn 2 SnO 4 nanoflower structure and the solid structure of the sphere. At an operating temperature of 380 °C, the response of the nanoflower structure to 50 ppm ethanol could reach 30.4, which was three times the corresponding structure.…”
Demands for the detection of harmful gas in daily life have arisen for a period and a gas nano-sensor acting as a kind of instrument that can directly detect gas has been of wide concern. The spinel-type nanomaterial is suitable for the research of gas sensors because of its unique structure. However, the existing instability, higher detection limit, and operating temperature of the spinel materials limit the extension of the spinel material sensor. This paper reviews the research progress of spinel materials in gas sensor technology in recent years and lists the common morphological structures and material sensitization methods in combination with previous works.
“…Ternary oxide zinc stannate (Zn 2 SnO 4 ) has fascinated massive interest of research due to their exceptional electrical and optical properties [1]. Zn 2 SnO 4 has larger band gap of 3.6 eV and higher electron mobility (10-15 cm 2 V −1 S −1 ) [1][2][3][4][5]. Ternary oxide materials are of superior property compared to binary oxides owing to their freedom to tune the properties such as work function, electrical conductivity, and band gap energy by varying its composition [1,3].…”
Section: Introductionmentioning
confidence: 99%
“…Owing to its feasible property, Zn 2 SnO 4 has prospective applications such as photocatalysis, transparent conducting oxides, sensors, and lithium ion batteries and in case of dye sensitized solar cells (DSSC), Zn 2 SnO 4 provides better control of carrier transport and collection which recovers the long term chemical stability of DSSC [2,3,[10][11][12]. There are many techniques to synthesize Zn 2 SnO 4 thermal evaporation, pulse laser deposition, spray pyrolysis, sputtering technique, and so forth [2], which requires extremely sophisticated laboratory and power consumption; thus in our case we utilized hydrothermal technique. The materialization of Zn 2 SnO 4 nanoparticles via hydrothermal process requires main processing variables such as reaction temperature and time, mineralizers enabling the formation reaction, and the pH of the slurry reaction in the autoclave.…”
Ternary oxide Zn2SnO4 has emerged as a promising material due to its tunable work function, band gap energy, and electric resistivity by simply varying the composition of the material. Zinc stannate nanoparticles were synthesized by green hydrothermal growth technique at 200°C for the reaction time of 24 h using stannic chloride pentahydrate (SnCl4·5H2O) and zinc chloride (ZnCl2) as precursors maintained at pH value of 8. X-ray diffraction analysis confirmed the phase purity and high crystalline nature of the synthesized sample. The estimated crystallite size was about 12.3 nm corresponding to the most prominent plane (311) using Scherrer equation. Morphology of the sample was characterized by SEM analysis, which confirmed the presence of small size nanoparticles. The optical property of synthesized sample was studied by using UV-visible and PL spectroscopy analysis. The derived optical band gap of 3.94 eV was found to be blue shifted as compared to bulk Zn2SnO4 (3.6 eV), which should be attributed to the quantum size effects. Room temperature photoluminescence spectrum showed emission bands at 397 nm and 468 nm.
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