“…Among these fluorous porphyrinoids, perfluorophenylporphyrin (TPPF 20 ), perfluorophthalocyanine (PcF 16 ) and perfluorophenylcorrole (CorF 15 ) are all commercially available in metallated and in their free-base forms. However, Diels-Alder and 1,3-dipolar cycloaddition reactions can be used to reduce TPPF 20 to the corresponding ChlF 20 , IbacF 20 and BacF 20 derivatives in high yields (15)(16)(17)(18). Because of their commercial availability and stability, the fluorinated porphyrinoids have become the center of attention of researchers developing advanced functional materials for applications such as sensors, photonic devices, solar cells, biomedical imaging, theranostics, catalysts, etc (10)(11)(12)(13).…”