One-Pot Synthesis of 5,6-Dihydro-4H-1,2-Oxazines by Cyclization of Ketoximes with Derivatives of Allylbenzene

The diverse nature of Chloramine-T, the sodium salt of N-chloro-p-toluenesulfonamide, abbreviated as CAT, acts as a source of halonium cation and nitrogen anion, and acts as both base and nucleophile. It reacts with broad range of functional groups and brings divergent molecular transformations to synthetic chemistry. CAT has also gained much recognition as a mild oxidant for several organic moieties and has been used as a versatile reagent for the estimation of various functional groups in analytical chemistry. This review relays the synthetic and analytic utility of CAT from different literature sources. As aspects of the synthetic utility of CAT have not previously been reviewed, this article gives a comprehensive profile of the CAT reagent for further research development.

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Chloramine-T in Organic Synthesis and Analysis of Organic Functional Groups: A Review

Sowmya

Lokanatha

Sudhir

et al. 2021

Aust. J. Chem.

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One-Pot Synthesis of 5,6-Dihydro-4H-1,2-Oxazines by Cyclization of Ketoximes with Derivatives of Allylbenzene

Abstract: A new series of 5,6-dihydro-4H-1,2-oxazines were synthesized via hetero Diels-Alder reaction of α-nitrosolefins with derivatives of allylbenzene. α-Nitrosoolefins were generated from ketoximes by the action of chloramine-T and triethylamine.

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Chloramine-T in Organic Synthesis and Analysis of Organic Functional Groups: A Review

Chloramine-T in Organic Synthesis and Analysis of Organic Functional Groups: A Review

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