On the Salt-Solutions in Microscopic Cavities in Granites

Abstract

Microscopic cavities were observed by Davy in 1822 and by Brewster in 1826 in various crystals of minerals and were more thoroughly studied by H. C. Sorby (J) who in 1858 from his observations drew certain conclusions as to the origin of minerals and rocks. Sorby examined first the microscopic structure of crystals which he had made under different conditions from solutions of various salts. The crystals contained microscopic cavities which were sometimes filled with a liquid, viz. that from which the crystals had been formed, the mother-liquor. If the crystals were formed at an elevated temperature the liquid enclosed in the cavities would contract when cooled and formed what looked like air bubbles. If the crystals were heated, the liquid would expand and would again fill the cavities. Some crystals would contain real air-bubbles or crystals of other salts; and all this as natural consequences of the varying conditions under which the crystals had been formed. Sorby then examined the crystals of minerals and found in them, and particularly in quartz in rocks, similar phenomena as those observed in the artificial crystals and therefrom drew his conclusions as to the origin of the minerals. In the sixth chapter he deals with minerals and rocks formed by combined action of heat and water, and he speaks particularly about the formation of granite.

Composition of fluid inclusions

“…"Turbid" feldspars also have large numbers of fluid inclusions (Folk, 1955). Some samples contain far more than 0.1 percent inclusion fluid, and the volatile constituents present in these inclusions, such as water and co::!, may cause major ambiguities and errors in analytical determinations of these constituents in rocks and minerals (Faber, 1941;Ermakov and Myaz, 1957). Fluid inclusions may also contribute as much as 100 ppm (parts per million) of each of several nonvolatile constituents to the total analysis of even " " .…”

“…Other workers have opened inclusions, prior to leaching, by decrepitation in a gas stream (Roedder, 1958, p. 264) ; decrepitation in a vacuum system (Wahler, 1956) ; crushing in vacuo (Roedder and others, 1963;Hall and Friedman, 1963) ; and crushing in a ball mill (Faber, 1941;Lamar and Shrode, 1953;Roedder, 1958;Goguel, 1963 and . 27 Numerous sources of contamination or loss in ball milling (and some other methods) are discussed by Roedder (1958), Goguel (1963), andSuscherskaya (1968).…”

“…The analytical methods used for determination of HC0 3 -1 and for C0 3 -2 in inclusions are not always capable of making these distinctions, and, in addition, the specific methods used are seldom stated. Faber (1941) analyzed the lea.chates obtained by large-scale ball milling (with flint balls in a flintlined mill) of 19 rocks and minerals, in connection with a detailed study of the sources of the water determined in various rock analysis procedures and an evaluation of their significance. He used glazed earthenware pots for the long-term leaching ( 4 to 6 weeks) and in part used decantation in place of filtering.…”