C URVES representing both the variation of contact E.M.F.'s and saturation photo currents with time have been taken on freshly cut sodium surfaces both in the best vacuum obtainable with a Gaede molecular pump and in vessels containing residual gases.The most striking characteristics of the photo-current-time curves is that they are of altogether different form according as the frequency of the light with which they are taken is that of the extreme ultra-violet or that of the visible spectrum. Thus, when tested with light of wave-length 5,461 A. the photo-sensitiveness of a freshly cut sodium surface is zero. It rises with time to a considerable value and finally falls again to zero When tested, however, with light of wave-length 2,535 A., this same surface shows a large initial photo-sensitiveness which falls off steadily with time to zero.These photo current-time curves taken in connection with the contact E.M.F .time curves are interpreted as follows: