On the Hot-Plate Welding of Reactively Compatibilized Acrylic-Based Composites/Polyamide (PA)-12

Abstract

Joining of dissimilar thermoplastics and their composites is a challenge for thermal welding techniques due to different melting points. Reactive welding with an auxiliary functional material can offer the clear opportunities to develop joining processes due to robustness to joining dissimilar thermoplastic polymers and their composites. The current study employed reactive compatibilization to offer the possibility of joining an acrylic-based glass fiber composite to polyamide (PA)-12 by applying a hot-tool welding technique. For this purpose, composite plates are fabricated by a typical vacuum infusion and thin layer thermoplastic films are formed by a thermostamping of PA12 granules. Subsequently, the reactive welding of the interposed PA12 sheet and Elium®-GMA-Glass composite is conducted by hot-plate welding. A glycidyl methacrylate (GMA) as a compatibilizing agent is copolymerized with methyl methacrylate Elium® resin. During the hot-tool welding process of dissimilar thermoplastic material, GMA can react with the polyamide end groups. The heat distribution at the Elium® GMA/PA-12 interface is responsible for obtaining a strong joint. This study focuses on the functionality of the compatibilizer on the welding of acrylic-based composites with polyamide (PA)-12 while varying the assembly temperature. The flatwise tensile test proved the effectiveness of GMA on the interface bounding. The excellent bounding incompatible polymers Elium® resin (PMMA) and PA12 was achieved at 200 °C.