“…However, untreated potato starch granules only allow oligosaccharides of no larger than 800-1000 Da to penetrate (Brown & French, 1977;Planchot, Roger, & Colonna, 2000) and thus have no voids to accommodate the probes, as shown in Figure 5A. The porosity of the starch matrix could be increased on heating, as suggested by a previous study in which gelatinization facilitated dye diffusion into the wheat starch matrix (Mira, Villwock, & Persson, 2007). These structures might entrap 20 kDa dextran and albumin but exclude the larger 70 kDa dextran, leading to the observed difference in relative diffusion coefficients (Figure 6B).…”