On the Crystal Structures of TiS3, ZrS3, ZrSe3, ZrTe3, HfS3, and HfSe3.

Furuseth, Sigrid; Brattås, Leif; Kjekshus, Arne; Andresen, Arne F.; Fischer, P.

doi:10.3891/acta.chem.scand.29a-0623

Cited by 268 publications

(160 citation statements)

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“…It belongs to space group C2h 2 (P21/m) with two formula units per unit cell. 87 Ti atoms, at the center of each prism, are coordinated to six S atoms at the corners and another two S atoms in neighbor chains. The prisms (basic coordination units) are linked via shared faces into an infinite chain parallel to the crystallographic b-axis, the direction with the 3 smallest Ti-Ti separation.…”

Section: Crystal Structure and Electronic Propertiesmentioning

confidence: 99%

“…The synthesis of the TMTCs started to be investigated in the sixties of the past century due to the great variety of possible applications associated with their wide range of physical properties 87,93,102,103 . One of the most interesting materials of the family is TiS3 due to its low toxicity and the abundance and moderate cost of its constituent elements.…”

Section: Synthesis and Bulk Characterizationmentioning

confidence: 99%

“…Zr atoms lie at the center of distorted trigonal prisms of S atoms, arranged in successive packing in infinite chains along the crystal b-axis; chains are held together in the c-axis by van der Waals forces. 87,168 ZrS3, in a nanobelt morphology, has been used in the fabrication of photodetectors showing photosensitivity to wavelengths from 405 nm to λ = 780 nm. The devices present ON/OFF current ratios of about 1.5 with dark current of 109 pA and response times around 390/800 ms (rise time/decay time).…”

Section: Optoelectronic Properties and Devicesmentioning

confidence: 99%

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Electronics and optoelectronics of quasi-1D layered transition metal trichalcogenides

et al. 2017

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The isolation of graphene and transition metal dichalcongenides has opened a veritable world to a great number of layered materials which can be exfoliated, manipulated, and stacked or combined at will. With continued explorations expanding to include other layered materials with unique attributes, it is becoming clear that no one material will fill all the post-silicon era requirements. Here we review the properties and applications of layered, quasi-one dimensional transition metal trichalcogenides (TMTCs) as novel materials for next generation electronics and optoelectronics. The TMTCs present a unique chain-like structure which gives the materials their quasi-one dimensional properties such as high anisotropy ratios in conductivity and linear dichroism. The range of band gaps spanned by this class of materials (0.2 eV-2 eV) makes them suitable for a wide variety of applications including field-effect transistors, infrared, visible and ultraviolet photodetectors, and unique applications related to their anisotropic properties which opens another degree of freedom in the development of next generation electronics. In this review we survey the historical development of these remarkable materials with an emphasis on the recent activity generated by the isolation and characterization of atomically thin titanium trisulfide (TiS3).

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Section: Crystal Structure and Electronic Propertiesmentioning

confidence: 99%

Section: Synthesis and Bulk Characterizationmentioning

confidence: 99%

Section: Optoelectronic Properties and Devicesmentioning

confidence: 99%

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Electronics and optoelectronics of quasi-1D layered transition metal trichalcogenides

et al. 2017

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“…( Furuseth, Brattas & Kjekshus, 1975;Keane & Ibers, 1991), whereas the Zr--Si distance is longer than that found in binary zirconium silicides (Schachner, Nowottny & Kudielka, 1954). The Zr--Zr separation of 3.697 (1)A is about 15% larger than in Zr metal.…”

Section: Teamentioning

confidence: 99%

Structure of the layer compound ZrSiTe

Bensch¹,

Dürichen²

1994

Acta Crystallogr C

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“…4 This work investigates ZrS 3 as a possible cathode material for use in Li thermal batteries. The synthesis of ZrS 3 has previously been reported by many authors [5][6][7][8] and the synthetic procedure (via a conventional solid state route) involved multiple firings at temperatures from 600…”

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Zirconium Trisulfide as a Promising Cathode Material for Li Primary Thermal Batteries

Giagloglou

Payne

Crouch

et al. 2016

J. Electrochem. Soc.

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In this work ZrS3 has been synthesized by solid state reaction in a sealed quartz tube and investigated as a candidate cathode material in Li thermal batteries. The structure of ZrS3 before and after cell testing has been studied using powder X-ray diffraction. A new spinel related material, LiZr2S4, has been identified as the product of the electrochemical process, which can be indexed to a = 10.452(8) Å cubic unit cell. The electrochemical properties of the batteries were investigated at 500°C against Li13Si4 by galvanostatic discharge and galvanostatic intermittent titration technique (GITT). In a thermal Li cell at 500°C a single voltage plateau of 1.70 V at a current density of 11 mA/cm2 was achieved with capacity of 357 mA h g−1. Therefore ZrS3 material has some promise as a cathode for Li thermal batteries.

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On the Crystal Structures of TiS3, ZrS3, ZrSe3, ZrTe3, HfS3, and HfSe3.

Cited by 268 publications

References 0 publications

Electronics and optoelectronics of quasi-1D layered transition metal trichalcogenides

Electronics and optoelectronics of quasi-1D layered transition metal trichalcogenides

Structure of the layer compound ZrSiTe

Zirconium Trisulfide as a Promising Cathode Material for Li Primary Thermal Batteries

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