Let X be a semiseparated Noetherian scheme with a dualizing complex D. We lift some well-known triangulated equivalences associated with Grothendieck duality to Quillen equivalences of model categories. In the process we are able to show that the Gorenstein flat model structure, on the category of quasi-coherent sheaves on X, is Quillen equivalent to the Gorenstein injective model structure. Also noteworthy is that we extend the recollement of Krause to hold without the Noetherian condition. Using a set of flat generators, it holds for any quasi-compact semiseparated scheme X. With this we also show that the Gorenstein injective quasi-coherent sheaves are the fibrant objects of a cofibrantly generated abelian model structure for any semiseparated Noetherian scheme X. Finally, we consider both the injective and (mock) projective approach to Tate cohomology of quasi-coherent sheaves. They agree whenever X is a semiseparated Gorenstein scheme of finite Krull dimension.