Abstract:Abstract:Electrical conduction in the temperature range of 120-370 K has been studied in sandwiched structures of Al/Ta 2 O 5 /Si. The tantalum oxide films were prepared by evaporation of tantalum on a p-Si crystal substrate, followed by oxidation at a temperature of 600˚C. The temperature-dependent current-voltage (I − V ) characteristics are explained on the basis of a phonon-assisted tunnelling model. The same explanation is given for I − V data measured on Ta 2 O 5 films by other investigators. From the co… Show more
“…Trap level extracted from the FE plot is lower than that determined from the zero electric field trap barrier height extrapolation for PFE. This behaviour indicates that the conduction mechanism in the MOS capacitor with 3.5 < t ox < 10 nm is governed by TTT, however, other mechanisms such as phonon-assisted tunnelling can also contribute [17].…”
Section: I-v-t Characteristicsmentioning
confidence: 95%
“…Leakage current mechanisms in metal-oxidesemiconductor (MOS) structures with Ta 2 O 5 have been extensively studied and also reviewed in the last decade [6,[9][10][11][12][13][14][15][16][17]. In most of the cases, Schottky emission or hopping has been reported as a dominant mechanism for low oxide electric fields [9,11], Poole-Frenkel emission (PFE) in the moderate electric field [6, 9-13, 15, 16], and in some cases the Fowler-Nordheim conduction mechanism has been observed for high electric fields in the oxide [9].…”
Section: Introductionmentioning
confidence: 99%
“…Direct tunnelling (DT) or trap-assisted tunnelling (TT) across the ultrathin SiO 2 -or a SiON-like IFL has been assumed [12,15]. However, in the recent papers, Schottky emission [14] and phonon-assisted tunnelling [17] have been reported to govern the leakage current through the Ta 2 O 5 grown by MOCVD and oxidation of evaporated Ta, respectively. Spassov et al [16] also pointed out that a gate electrode deposition technique influences the dominant conduction mechanism in rf-sputtered Ta 2 O 5 .…”
Leakage conduction mechanisms in Ru/Ta 2 O 5 /SiON/Si structures with rf-sputtered Ta 2 O 5 with thicknesses ranging from 13.5 to 1.8 nm were systematically studied. Notable reaction at the Ru/Ta 2 O 5 interface was revealed by capacitance-voltage measurements. Temperature-dependent current-voltage characteristics suggest the bulk-limited conduction mechanism in all metal-oxide-semiconductor structures. Under gate injection, Poole-Frenkel emission was identified as a dominant mechanism for 13.5 nm thick Ta 2 O 5 . With an oxide thickness decreasing down to 3.5 nm, the conduction mechanism transforms to thermionic trap-assisted tunnelling through the triangular barrier. Under substrate injection, the dominant mechanism gradually changes with decreasing thickness from thermionic trap-assisted tunnelling to trap-assisted tunnelling through the triangular barrier; Poole-Frenkel emission was not observed at all. A 0.7 eV deep defect level distributed over Ta 2 O 5 is assumed to be responsible for bulk-limited conduction mechanisms and is attributed to H-related defects or oxygen vacancies in Ta 2 O 5 .
“…Trap level extracted from the FE plot is lower than that determined from the zero electric field trap barrier height extrapolation for PFE. This behaviour indicates that the conduction mechanism in the MOS capacitor with 3.5 < t ox < 10 nm is governed by TTT, however, other mechanisms such as phonon-assisted tunnelling can also contribute [17].…”
Section: I-v-t Characteristicsmentioning
confidence: 95%
“…Leakage current mechanisms in metal-oxidesemiconductor (MOS) structures with Ta 2 O 5 have been extensively studied and also reviewed in the last decade [6,[9][10][11][12][13][14][15][16][17]. In most of the cases, Schottky emission or hopping has been reported as a dominant mechanism for low oxide electric fields [9,11], Poole-Frenkel emission (PFE) in the moderate electric field [6, 9-13, 15, 16], and in some cases the Fowler-Nordheim conduction mechanism has been observed for high electric fields in the oxide [9].…”
Section: Introductionmentioning
confidence: 99%
“…Direct tunnelling (DT) or trap-assisted tunnelling (TT) across the ultrathin SiO 2 -or a SiON-like IFL has been assumed [12,15]. However, in the recent papers, Schottky emission [14] and phonon-assisted tunnelling [17] have been reported to govern the leakage current through the Ta 2 O 5 grown by MOCVD and oxidation of evaporated Ta, respectively. Spassov et al [16] also pointed out that a gate electrode deposition technique influences the dominant conduction mechanism in rf-sputtered Ta 2 O 5 .…”
Leakage conduction mechanisms in Ru/Ta 2 O 5 /SiON/Si structures with rf-sputtered Ta 2 O 5 with thicknesses ranging from 13.5 to 1.8 nm were systematically studied. Notable reaction at the Ru/Ta 2 O 5 interface was revealed by capacitance-voltage measurements. Temperature-dependent current-voltage characteristics suggest the bulk-limited conduction mechanism in all metal-oxide-semiconductor structures. Under gate injection, Poole-Frenkel emission was identified as a dominant mechanism for 13.5 nm thick Ta 2 O 5 . With an oxide thickness decreasing down to 3.5 nm, the conduction mechanism transforms to thermionic trap-assisted tunnelling through the triangular barrier. Under substrate injection, the dominant mechanism gradually changes with decreasing thickness from thermionic trap-assisted tunnelling to trap-assisted tunnelling through the triangular barrier; Poole-Frenkel emission was not observed at all. A 0.7 eV deep defect level distributed over Ta 2 O 5 is assumed to be responsible for bulk-limited conduction mechanisms and is attributed to H-related defects or oxygen vacancies in Ta 2 O 5 .
“…The object of the PhAT investigation has also been extensively studied in our and co-workers' papers: for polymers films [5,11,71], for MEH-PPV diodes [6], polyacetylene nanofibers [7], some oxide nanowires or films [8,10], carbon nanotube networks [12,13], graphene nanoribbons and graphene oxides [57], and polydiacetylene crystals [72]. Some authors have currently applied the PhAT model that we propose and Eq.…”
Section: Discussionmentioning
confidence: 99%
“…However, the focus of attention here was assigned to variable range hopping (VRH) [3,4] as the dominant transport mechanism in these materials, and the model is based only on the temperature dependences of conductivity. A number of articles have appeared in the last decade where the electrical-field induced phononassisted tunneling (PhAT) model has been suggested to describe the temperature dependent conductivity in polymers [5][6][7], inorganic materials [8][9][10][11] and carbon nanotubes [12,13]. The said PhAT model is based on the quantum-mechanical theory, and it can properly explain not only the temperature dependences of conductivity, but also the temperature-dependent current-voltage characteristics in a wide range of temperatures and electric field strengths.…”
Abstract:We review and compare two models recently used to describe electronic transport in polymer fibers/nanotubes and carbon nanotubes including graphene nanoribbons, namely, variable range hopping (VRH) in different versions and their modifications on the one hand and electric-field-induced phononassisted tunneling (PhAT) on the other hand. The VRH model is mainly approved on behalf of the results of temperature dependences. However, the field dependencies of the conductivity in the framework of this model remain practically unexplained. At the same time, the PhAT model describes properly not only temperature dependence of conductivity measured in a wide temperature range, but also conductivity/current dependences on field strength using the same set of parameters characterizing the materials
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