Oligomers and Pleionomers of Synthetic Fiber‐Forming Polymers

Zahn, Helmut; Gleitsman, G. B.

doi:10.1002/anie.196304101

Cited by 35 publications

(11 citation statements)

References 114 publications

(18 reference statements)

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“…Uniform oligoesters are useful model compounds to study and understand, for example, the crystallization behavior of the corresponding high-molecular-weight polymers. The first pioneering reports describing the synthesis of uniform oligoesters date back more than 20-30 years and were published by Zahn 5 and Wegner. 42 Zahn et al prepared uniform ethylene terephthalate oligomers containing up to ten repeat units via a synthetic strategy that combined simple repetitive synthesis of elementary building blocks with fragment condensation to prepare the final oligomers of the desired length.…”

Section: Methodsmentioning

confidence: 99%

“…However, an increasing number of synthetic methods has become available that allows access to uniform and sequence-specific non-natural oligomers. In the broadest sense, uniform non-natural oligomers are of interest (i) as model compounds that can help to establish structure-property relationships for the corresponding high-molecular-weight polymers, [4][5][6][7] and (ii) as foldamers. [8][9][10] As model compounds, uniform, nonnatural oligomers can facilitate the analysis of comonomer distribution and stereochemistry of high-molecularweight copolymers and allow to study the influence of these parameters on e.g.…”

Section: Introductionmentioning

confidence: 99%

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Synthesis of Uniform, Non-Natural Oligomers

Franz¹,

Kreutzer²,

Klok³

2006

Synlett

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Oligomers with well-defined chain lengths are of interest as foldamers, are important as model compounds for high-molecular-weight polymers and find application in electrooptic and sensory devices. This account presents an overview of the strategies that are available for the synthesis of eight important classes of uniform oligomers. The continuous refinement of the synthetic methods allows the preparation of ever longer oligomers in higher yields and also makes it possible to introduce special functional groups. These improvements could lead to materials with new or improved properties and underline the importance of synthetic organic chemistry for the development of new functional materials.

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Section: Methodsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Synthesis of Uniform, Non-Natural Oligomers

Franz¹,

Kreutzer²,

Klok³

2006

Synlett

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“…Pioneering synthetic work in this field was carried out by Zahn et al (Pénisson & Zahn, 1970;Zahn & Gleitsman, 1963), followed by Haslin et al (Haslin et al, 1980) and more recently by Brooke et al (Brooke et al, 2002). Possible PET oligomers can have free carboxylic group and hydroxyl group or both of them on the ends of the chain (Fig.…”

Section: Synthesis and Characterizationmentioning

confidence: 99%

Synthesis and characterization of polyethylene terephthalate (PET) precursors and potential degradation products: Toxicity study and application in discovery of novel PETases

et al. 2021

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This is a PDF file of an article that has undergone enhancements after acceptance, such as the addition of a cover page and metadata, and formatting for readability, but it is not yet the definitive version of record. This version will undergo additional copyediting, typesetting and review before it is published in its final form, but we are providing this version to give early visibility of the article. Please note that, during the production process, errors may be discovered which could affect the content, and all legal disclaimers that apply to the journal pertain.

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“…Also contributing to the complexity is the formation of cyclic oligomers corresponding to the following formula [36]:…”

Section: Equilibrium and Rate Constantsmentioning

confidence: 99%

Polyamides

Herzog¹,

Kohan²,

Mestemacher³

et al. 2013

Ullmann's Encyclopedia of Industrial Chemistry

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The article contains sections titled: 1. Introduction 2. Nomenclature 3. General Considerations in Polyamidation 3.1. Molecular Mass 3.2. Equilibrium and Rate Constants 3.3. Effects of Monomer Structure 3.4. Amide Interchange 3.5. Structure‐Property Considerations 4. Other Polymerization Techniques 4.1. Variants of Hydrolytic Polymerization 4.2. Interfacial and Solution Polymerization 4.3. Ionic Polymerization 4.4. Solid‐Phase Polymerization 5. Commercial Processes 5.1. PA 46 5.2. PA 66 5.2.1. Batch Production 5.2.2. Continuous Production 5.3. Other AABB‐Polyamides 5.4. PA 6 5.5. PA 11 5.6. PA 12 6. Properties 6.1. Properties of Unmodified Polyamides 6.2. Copolymerization 6.3. Modification by Additives 6.3.1. Filled and Reinforced Polyamides 6.3.2. Blends and Alloys 6.3.3. Flame‐Retardant Polyamides 6.3.4. Conductive Polyamides 6.3.5. Other Formulations 7. Processing 8. Uses 9. Ecological Aspects and Toxicology 9.1. Recycling 9.2. Polyamide Monomers 9.3. Other Aspects 10. Economic Aspects

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Oligomers and Pleionomers of Synthetic Fiber‐Forming Polymers

Cited by 35 publications

References 114 publications

Synthesis of Uniform, Non-Natural Oligomers

Synthesis of Uniform, Non-Natural Oligomers

Synthesis and characterization of polyethylene terephthalate (PET) precursors and potential degradation products: Toxicity study and application in discovery of novel PETases

Polyamides

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