Self-ordered second-component clusters in solid solutions on the basis of ferroelectric perovskites: Nb clusters in KTaO 3 AIP Conf.Abstract. The large-scale modeling of the atomic and electronic structure of KNb^Tai-ajOa (KTN) perovskite solid solutions is performed using the Intermediate Neglect of the Differential Overlap (INDO) method based on the Hartree-Fock formalism. It is found that periodic Nb impurities in KTaOs reveal coherent off-center displacements already at the smallest calculated concentration, or-0.125. The calculated magnitude of < 111 > Nb off-center displacement is 0.27 a.u., which is close to the XAFS observation at 70 K and #=0.09. In contrast, Ta impurities in KNbOa remain on-center, due to higher ionicity of Ta, as compared to Nb. Using the calculated energy gain caused by the off-center displacements of Nb atoms, the non-empirical Ginzburg-Landau-Devonshire functional with concentration-dependent coefficients is constructed. Analysis of INDO results for several Nb concentrations in KTN allows calculate the lowest critical Nb concentration, # cr =0.025, corresponding to the quantum displacive limit for the paraelectric-ferroelectric transition at 0 K. This value is only slightly higher than the experimental one.