Direct catalytic cracking of crude oil to chemicals (ccCOTC)
has
become the development trend in the petrochemical industry. A riser
is one of the key reactors in a ccCOTC process. In this work, a two-fluid
model (TFM) was used to simulate a relationship between the reactor
geometry and gas–solid flow in a typical riser (inside diameter
of 17 mm and height of 4.5 m) established in our laboratory, with
the aim of improving chemical yield and optimizing the reactor geometry
in a ccCOTC process. The effects of key geometric parameters, including
the angle between an oblique pipe for catalyst return and the vertical
riser (α), the distance between the nozzle orifice and catalyst
return oblique pipe (L), the ratio of height to diameter
in the prelifting zone (H/D), and
the number of catalysts returning to oblique pipes (n), on the distribution of catalyst particles and product profiles
were studied. An optimized reactor geometry was proposed according
to the index of gas–solid dispersion evenness. To further know
the effect of the riser geometry on the product distribution, the
two-fluid model (TFM) coupled with a four-lumped kinetic model was
used to predict the cracking product profiles along the riser axial.
It was found that the ccCOTC riser can remarkably enhance the yield
of target chemicals (C2–C4 olefins, benzene, toluene, and xylene),
which was approximately 3.1% higher than the result from the pilot
test (using the riser before geometry optimization). This work could
provide fundamental support on the design of a reactor to maximize
light olefins and monocyclic aromatic hydrocarbons in the ccCOTC process.