“…Aluminum is the most common metal and the third-most abundant element in the Earth’s crust. − As a result, aluminum (oxy)hydroxide polymorphs, such as gibbsite (α-Al(OH) 3 , sometimes designated as γ-Al(OH) 3 ), bayerite (β-Al(OH) 3 , sometimes as α-Al(OH) 3 ), nordstrandite (Al(OH) 3 ), doyleite (Al(OH) 3 ), boehmite (γ-AlOOH), and diaspore (α-AlOOH) are abundant minerals in soils and dominate aluminum ores such as bauxites. Similar to other types of metal hydroxide materials such as layered double hydroxides (LDHs), − various aluminum (oxy)hydroxide phases have been deployed widely as adsorbents, fire retardants, coatings, catalysts, and luminescence materials. − These phases are also important precursors to various alumina products such as α-, γ-, δ-, θ-, and χ-Al 2 O 3 . ,− Understanding the crystallization and phase transformation pathways of the aluminum (oxy)hydroxide polymorphs is thus important to geochemistry, environmental science, energy storage, catalysis, biomedicine, industrial processing, and even nuclear waste treatment. ,− In particular, various aluminum (oxy)hydroxides, which dominate certain high-level tank waste sludges, are problematic due to their much lower solubility and variable phase transformation properties. ,,− …”