1961
DOI: 10.1515/zna-1961-1131
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Notizen: Nachweis der Koordinationsänderung bei der Borsäureanomalie

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“…48A for tetrahedral B04 units (l15). Until the recent work of Mozzi and Warren (77) the areas under the peaks have not been accurate enough to measure coordination number s dire ctly; values of NB04 so obtained tended (7,46) invariably to be vastly larger than the more accurate values derived from NMR (next chapter). The improved methods of Mozzi and Warren (see below ) have not yet been applied to multicomponent borate glas se s containing both B03 and B04 units, however.…”
Section: X-ray Diffraction Studiesmentioning
confidence: 99%
“…48A for tetrahedral B04 units (l15). Until the recent work of Mozzi and Warren (77) the areas under the peaks have not been accurate enough to measure coordination number s dire ctly; values of NB04 so obtained tended (7,46) invariably to be vastly larger than the more accurate values derived from NMR (next chapter). The improved methods of Mozzi and Warren (see below ) have not yet been applied to multicomponent borate glas se s containing both B03 and B04 units, however.…”
Section: X-ray Diffraction Studiesmentioning
confidence: 99%