Nonthermal effects in H-doped tungsten at high electronic temperatures

Yu, Pengfei; Pan, Bicai

doi:10.1016/j.jnucmat.2022.153896

Cited by 2 publications

(1 citation statement)

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“…Moreover, considering the practical operating environment of W-PFMs within a Tokomak, the plasma inside the reactor reaches an ultrahigh temperature of approximately 10 9 K. This high-temperature plasma is actually a high-temperature black body that continuously emits a significant quantity of high-energy photons [15][16][17]. When high-energy photons irradiate W-PFMs, they excite some of the electrons within the material, resulting in W-PFMs entering an electronically excited state [17]. The physical behavior of materials in such an electronically excited state can deviate significantly from that observed in the electronic ground state [18,19].…”

Section: Introductionmentioning

confidence: 99%

Electronically Temperature-Dependent Interplay between He and Trivacancy in Tungsten Plasma-Facing Materials

Fu,

Pan

2024

Materials

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Both microvoids and helium (He) impurities are widely present in tungsten (W) plasma-facing materials (PFMs), where the interaction between microvoids and He atoms has led to the intriguing development of microvoids. In this paper, we comprehensively investigated the interaction between He atoms and trivacancy (V3), a fundamental microvoid in W-PFMs, at the level of tight-binding theory. Our study showed that He atoms can catalyze the decomposition of the original V3 or facilitate its transformation into another V3 variant. We propose that a He atom near the V3 defect induces significant changes in the distribution of d-electron charges within the W atoms lining the inner wall of the V3 defect, making the W atom nearest to this He atom cationic and the other W atoms anionic. The attractive interaction between them promotes the decomposition and deformation of V3. As electronic excitation increases, the ionization of W atoms on the V3 wall gradually intensifies, thereby enhancing the cationic characteristics of the W atoms closest to the He atom. This process also prompts other W atoms to shift from anions to cations, leading to a transition in the electrostatic interactions between them from attraction to repulsion. This transformation, driven by electronic excitation, plays a significant inhibitory role in the decomposition and deformation of V3.

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