In this article, we achieved several non-naturally reductive Einstein metrics on exceptional simple Lie groups, which are formed by the decomposition arising from general Wallach spaces. By using the decomposition corresponding to the two involutive automorphisms, we calculated the non-zero coefficients in the expression for the components of Ricci tensor with respect to the given metrics. The Einstein metrics are obtained as solutions of systems polynomial equations, which we manipulate by symbolic computations using Gröbner bases.