“…Therefore, the material key curve is a great tool to investigate changes in the constraint level during crack initiation. For the correct application of the material key curve, the load separation principle has to be verified beforehand, as presented for several polymers in the literature [ 11 , 14 , 15 , 16 , 17 , 18 , 19 , 20 , 21 , 22 ]. The material key curve is based on the load separation principle [ 9 , 23 , 24 ], in which the load, P, can be expressed as the product of two independent functions for a defined geometry, material and constraint (in the plastic region during a fracture test on a cracked specimen) [ 9 ]: where G is the geometry function, H the material deformation function, a the notch length, W the specimen width, and u pl the plastic displacement.…”