Nitrogen-doped porous carbon material derived from metal–organic gel for small biomolecular sensing

Abstract

A simple preparation method of N-doped PCM via direct carbonization of nitrogen containing metal-organic gel was demonstrated. The resultant N-PCM, with high surface area, mesoporosity, and high UV absorption ability, was used as a matrix to assist small-biomolecule sensing in laser desorption/ionization mass spectrometry.

A Copper Metal–Organic Hydrogel as a Catalyst for SO2 and CO2 Fixation under Ambient Conditions

“…In recent years, metal–organic gels (MOGs) have attracted a great deal of attention due to their potential application in sensing, molecular recognition, catalysis, drug delivery, and dye adsorption, Low molecular weight MOGs are formed due to various non‐covalent interactions which are responsible for the rapid self‐assembly process of the discrete metal complexes and formation of the microstructures where a significant amount of solvent molecules are entrapped inside the network. These weak non‐covalent interactions, as well as the microstructure, can be easily deformed through the external stimuli, and material can undergo the gel to sol transition or vice‐versa.…”

Surface Siloxane-Modified Silica Materials Combined with Metal–Organic Frameworks as Novel MALDI Matrixes for the Detection of Low-MW Compounds

“…Both the composite matrixes had ultrahigh tolerance for salt concentrations. Therefore, SBA-15@APTES@MOF and SiO 2 @APTES@MOF can be used as matrixes for the detection of highly salty analytes without an additional desalting step …”

“…Therefore, SBA-15@APTES@MOF and SiO 2 @APTES@MOF can be used as matrixes for the detection of highly salty analytes without an additional desalting step. 52 Figure 6. MALDI-TOF MS spectra of proline (8.7 mM) with the matrix of (A) SBA-15@APTES@MOF and (B) SiO 2 @APTES@MOF in NaCl concentrations from 0 to 1000 mM.…”

Combined Analysis Based on a Crystalline Sponge Method

“…For example, metal-organic frameworks (MOFs) are very similar to CS in terms of crystallinity and the presence of nanopores for absorbing molecules. [25][26][27] Huang, Shih, and co-workers firstly reported 28 the use of MOFs for SALDI, and cage-type MIL-100(Fe) MOFs were used as the matrix in SALDI to detect nonpolar polycyclic aromatic hydrocarbons (PAHs) as shown in Fig. 7.…”