New U-Pb SHRIMP-II zircon intrusion ages of the Cana Brava and Barro Alto layered complexes, central Brazil: constraints on the genesis and evolution of the Tonian Goias Stratiform Complex
Abstract:The Cana Brava, Niquelândia and Barro Alto complexes (Goiás, central Brazil) are three of the largest mafic-ultramafic layered complexes in the world and their origin has been a matter of debate for several decades. One hypothesis suggests that Niquelândia and Barro Alto were both formed by two distinct igneous events at 1.3 Ga and at 790Ma and were later overlapped during tectonic exhumation at 650 Ma; according to this reconstruction Cana Brava belongs to the youngest intrusion at 790 Ma. A second hypothesis… Show more
“…The Tonian Goiás Stratiform Complex is located in the northeastern sector of the Goiás State and is considered one of the biggest mafic to ultramafic complexes worldwide. The emplacement of the Tonian Goiás Stratiform Complex is believed to be Mesoproterozoic to Neoproterozoic in age (800-770 Ma; Pimentel et al, 2000;Giovanardi et al, 2017), although its geodynamic setting is still a matter of debate. Many authors (e.g., Pimentel et al, 2004Pimentel et al, , 2006Giovanardi et al, 2017) suggested that continental rift and back-arc extension in continental crust settings are the most appropriate geodynamic scenarios for the Tonian Goiás Stratiform Complex emplacement.…”
The Santa Fé Ni-Co deposit is a major undeveloped lateritic deposit located in the Goiás State of Central Brazil. The deposit comprises two properties that together have indicated resources of 35.7 million tonnes (Mt), grading 1.14% Ni and 0.083% Co, and inferred resources of 104.3 Mt at 1.03% Ni and 0.054% Co. The laterite was derived from Late Cretaceous alkaline ultramafic lithologies that experienced an initial silicification from Eocene to Oligocene, followed by lateritization and partial reworking in Miocene-Pliocene. The deposit is characterized both by oxide- and phyllosilicate-dominated ore zones. In the former, Ni- and Co-bearing hematite and goethite dominate the supergene mineralogical assemblage, while ore-bearing Mn oxyhydroxides occur as minor components. In the phyllosilicate-dominated horizons the major Ni-carrying phase is chlorite.
Multivariate statistical analyses (factor analysis and principal components analysis) conducted on the drill core assay database (bulk-rock chemical analyses) showed that significant differences exist between Ni and Co distributions. The Ni distribution is not controlled by any clear geochemical correlation. This is because the highest Ni concentrations have been measured in the ferruginous and in the ochre saprolite zones, where Ni-bearing minerals (chlorite and goethite) are mostly associated with reworked material and only in a limited way, with zones affected by in situ ferrugination. Cobalt has an atypical statistical distribution at Santa Fé if compared with other laterites, correlated not only with Mn but also with Cr in the majority of the laterite facies. From microchemical analyses on several potential Co-bearing minerals, it was found that the Co-Cr association is related to elevated Co contents in residual spinels, representing unweathered phases of the original parent rock now included in the laterite. This element distribution is atypical for Ni-Co laterite deposits, where Co is normally associated with Mn in supergene oxyhydroxides. In the case of the Santa Fé laterite, the Co concentration in spinels is likely related to magmatic and postmagmatic processes that affected the original parent rock before lateritization, specifically (1) orthomagmatic enrichment of Co in chromite, due to its high affinity to spinels in alkaline melts, and (2) trace elements (i.e., Co, Mn, Ni, and Zn) redistribution during the hydrothermal alteration of chromite into ferritchromite. The Santa Fé deposit represents a good example of how the prelateritic evolution of a parent rock strongly affects the efficiency of Co mobilization and enrichment during supergene alteration. Based on the interpretation of metallurgical test work, a fraction of total Co between 20 and 50% is locked in spinels.
“…The Tonian Goiás Stratiform Complex is located in the northeastern sector of the Goiás State and is considered one of the biggest mafic to ultramafic complexes worldwide. The emplacement of the Tonian Goiás Stratiform Complex is believed to be Mesoproterozoic to Neoproterozoic in age (800-770 Ma; Pimentel et al, 2000;Giovanardi et al, 2017), although its geodynamic setting is still a matter of debate. Many authors (e.g., Pimentel et al, 2004Pimentel et al, , 2006Giovanardi et al, 2017) suggested that continental rift and back-arc extension in continental crust settings are the most appropriate geodynamic scenarios for the Tonian Goiás Stratiform Complex emplacement.…”
The Santa Fé Ni-Co deposit is a major undeveloped lateritic deposit located in the Goiás State of Central Brazil. The deposit comprises two properties that together have indicated resources of 35.7 million tonnes (Mt), grading 1.14% Ni and 0.083% Co, and inferred resources of 104.3 Mt at 1.03% Ni and 0.054% Co. The laterite was derived from Late Cretaceous alkaline ultramafic lithologies that experienced an initial silicification from Eocene to Oligocene, followed by lateritization and partial reworking in Miocene-Pliocene. The deposit is characterized both by oxide- and phyllosilicate-dominated ore zones. In the former, Ni- and Co-bearing hematite and goethite dominate the supergene mineralogical assemblage, while ore-bearing Mn oxyhydroxides occur as minor components. In the phyllosilicate-dominated horizons the major Ni-carrying phase is chlorite.
Multivariate statistical analyses (factor analysis and principal components analysis) conducted on the drill core assay database (bulk-rock chemical analyses) showed that significant differences exist between Ni and Co distributions. The Ni distribution is not controlled by any clear geochemical correlation. This is because the highest Ni concentrations have been measured in the ferruginous and in the ochre saprolite zones, where Ni-bearing minerals (chlorite and goethite) are mostly associated with reworked material and only in a limited way, with zones affected by in situ ferrugination. Cobalt has an atypical statistical distribution at Santa Fé if compared with other laterites, correlated not only with Mn but also with Cr in the majority of the laterite facies. From microchemical analyses on several potential Co-bearing minerals, it was found that the Co-Cr association is related to elevated Co contents in residual spinels, representing unweathered phases of the original parent rock now included in the laterite. This element distribution is atypical for Ni-Co laterite deposits, where Co is normally associated with Mn in supergene oxyhydroxides. In the case of the Santa Fé laterite, the Co concentration in spinels is likely related to magmatic and postmagmatic processes that affected the original parent rock before lateritization, specifically (1) orthomagmatic enrichment of Co in chromite, due to its high affinity to spinels in alkaline melts, and (2) trace elements (i.e., Co, Mn, Ni, and Zn) redistribution during the hydrothermal alteration of chromite into ferritchromite. The Santa Fé deposit represents a good example of how the prelateritic evolution of a parent rock strongly affects the efficiency of Co mobilization and enrichment during supergene alteration. Based on the interpretation of metallurgical test work, a fraction of total Co between 20 and 50% is locked in spinels.
“…4 samples from Cana Brava, 3 from Barro Alto and 3 from Niquelândia were selected for analyses in zircons of the Lu-Hf and U-Pb isotope systematics. Some of these samples were already investigated for U-Pb analysis (Correia et al, 2007(Correia et al, , 2012Giovanardi et al, 2015Giovanardi et al, , 2017b. When possible, Lu-Hf analyses were carried out onto the same crystals and domains analyzed for U-Pb.…”
Section: Samplesmentioning
confidence: 99%
“…2). U-Pb SHRIMP ages from the three samples were discussed in Giovanardi et al (2017b). Samples CB1175 and CB1382 are hydrous granoblastic gabbros with foliation parallel to the complex direction derived by the alignment of pyroxenes and plagioclases.…”
Section: Samplesmentioning
confidence: 99%
“…While the LS is formed by ultramafics and gabbros showing increasing crustal contamination along the stratigraphy (Correia et al, 1997(Correia et al, , 2012Rivalenti et al, 2008;Giovanardi et al, 2017a), the US consists of anorthosites and olivine-gabbros and is considered uncontaminated (Rivalenti et al, 2008;Correia et al, 2012). This difference between the two units has generated two opposite models of formation: the two-intrusions model, where the LS and US are considered separated intrusions of Neoproterozoic and Mesoproterozoic ages, respectively (Pimentel et al, 2004(Pimentel et al, , 2006Ferreira Filho et al, 2010;Della Giustina et al, 2011) and the one-intrusion model, in which the US crystallized from an anorthositic melt segregated from the precipitation of the LS ultramafics (Rivalenti et al, 2008;Correia et al, 2012;Giovanardi et al, 2017b).…”
Section: Introductionmentioning
confidence: 99%
“…Therefore, new Lu-Hf isotopic analyses of zircons were carried out to constrain the contamination of LS and US in the three fragments of the TGSC. Analyses were also performed on previously SHRIMP U-Pb dated zircons from Giovanardi et al (2017b) and Correia et al (2007Correia et al ( , 2012.…”
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