New strategies for the synthesis of partially fluorinated acrylic polymers as possible materials for the protection of stone monuments

Mazzola, Marco; Frediani, Piero; Bracci, Susanna; Salvini, Antonella

doi:10.1016/s0014-3057(03)00110-1

Cited by 48 publications

(26 citation statements)

References 20 publications

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“…Polymers based on various acrylics, which are known as Paraloids, are widely used in the conservation of monuments. Polyacrylics are synthesized by the addition polymerization of the corresponding monomers 44…”

Section: Different Kinds Of Polymers For Monument Protectionmentioning

confidence: 99%

Polymeric coatings for protection of historic monuments: Opportunities and challenges

Sadat‐Shojai

Ershad‐Langroudi

2009

J of Applied Polymer Sci

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The conservation and protection of historic monuments or culturally significant structures have recently attracted much attention from material scientists. This review is given of the various aspects of the monuments protection such as the main reasons of damaging and spoiling of the historical monuments, the factor of contact angle as one of the essential parameters in the selection of polymeric coatings, and some of usual types of polymeric materials used for monument protection. There has been growing interest in developing novel materials for using in protective fields. Nowadays, the polymeric coatings, especially those with high hydrophobicity, are widely used to decrease or even stop further deterioration of historical monument. This review presents some of the most well‐known polymers used as protective materials such as acrylics, alkoxysilanes, fluorinated polymers, and hybrid organic–inorganic coatings. Furthermore, hybrid organic–inorganic coatings as a new class of materials are increasingly interesting materials because of their extraordinary properties deriving from the combination of the different building blocks and it is attempted to focus on this materials. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009

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Section: Different Kinds Of Polymers For Monument Protectionmentioning

confidence: 99%

Polymeric coatings for protection of historic monuments: Opportunities and challenges

Sadat‐Shojai

Ershad‐Langroudi

2009

J of Applied Polymer Sci

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“…However, the slowing down of the ageing process of historic stone relics is still mostly achieved through the use of organic coating treatments such as water-repellents, acid-repellents, and consolidants to preserve damaged historic stones or to protect un-damaged historic stone relics (Price, 1996;Striegel et al, 2003). Presently, the majority of materials that have been tried in the conservation of stone relics include epoxies (Cardiano et al, 2005), acrylics (Mazzola et al, 2003;Princi and Vicini, 2008), organic silicon compounds (Tarasov, 2001;Cardiano et al, 2005), fluorinecontaining polymers (Rizzarelli et al, 2001;Mazzola et al, 2003;Liang et al, 2009), etc. These materials can play a certain role in the protection of the stone relics, but they also have some inadequacies and defects, such as shorter life, poorer compatibility, or changes in the aspect of the treated historic stone sites (Melo et al, 1999;Borgia et al, 2001).…”

Section: Introductionmentioning

confidence: 99%

Advanced design of Chinese traditional materials for the conservation of historic stone buildings

Liu¹,

Liu²,

Zeng³

et al. 2011

Journal of Archaeological Science

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“…For example, partially fluorinated acrylic polymers synthesized by Frediani and co-workers [8] may be exploited in the protection of stone monuments.…”

Section: Introductionmentioning

confidence: 99%

Characterization of a low-wettable surface based on perfluoroalkyl acrylate copolymers

Yang

Yao

Chen

et al. 2006

Journal of Fluorine Chemistry

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New strategies for the synthesis of partially fluorinated acrylic polymers as possible materials for the protection of stone monuments

Cited by 48 publications

References 20 publications

Polymeric coatings for protection of historic monuments: Opportunities and challenges

Polymeric coatings for protection of historic monuments: Opportunities and challenges

Advanced design of Chinese traditional materials for the conservation of historic stone buildings

Characterization of a low-wettable surface based on perfluoroalkyl acrylate copolymers

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