New spiro-borane and spiro-borate derived from dipyrromethane and their H/D exchange properties

Subramaniyan, Vasudevan; Mani, Ganesan

doi:10.1016/j.poly.2020.114612

Cited by 3 publications

(2 citation statements)

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“…For example, Mani et al described the preparation of spiroborane and spiroborate from diethyldipyrromethane using BH 3 •THF or BF 3 •Et 2 O as the boron source (Scheme 40). 82 The assynthesized all-nitrogen-coordinated borane is a carbon acid 83 These polycyclic aminoboranes feature a crown ether-like structure in which the nitrogen atoms are linked with ethylene or trimethylene bridges while the central borons adopt a trigonal or pyramidal geometry. Interestingly, the preparation of different-membered tris(amino)boranes required different methods, and the obtained products also differed in shape.…”

Section: Tetrahedral All-nitrogen-coordinated Boratesmentioning

confidence: 99%

“…For example, Mani et al described the preparation of spiroborane and spiroborate from diethyldipyrromethane using BH 3 ·THF or BF 3 ·Et 2 O as the boron source (Scheme ). The as-synthesized all-nitrogen-coordinated borane is a carbon acid that readily gives borate upon treatment with bases and undergoes rapid acid-catalyzed H/D exchange with D 2 O.…”

Section: Tetrahedral All-nitrogen-coordinated Boratesmentioning

confidence: 99%

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“Homoleptic” Tetracoordinate Boron Compounds

Li,

Song

2024

Inorg. Chem.

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Metrics & MoreArticle Recommendations * sı Supporting Information ABSTRACT: "Homoleptic" tetracoordinate boron compounds, in which the central boron atom links to four identical atoms, are a special and important family of boron compounds. During the past decades, they have been extensively employed in inorganic, organic, macromolecular, and materials chemistry. Many of them exhibit a diverse range of outstanding properties, and therefore, the synthesis and application of those compounds have emerged as a hot research topic in modern boron chemistry. This review summarizes and discusses the "homoleptic" tetracoordinate boron compounds, which are organized according to the kinds of atoms coordinated to the central boron.

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Section: Tetrahedral All-nitrogen-coordinated Boratesmentioning

confidence: 99%

Section: Tetrahedral All-nitrogen-coordinated Boratesmentioning

confidence: 99%