2019
DOI: 10.1016/j.poly.2019.06.053
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New Ru(II)–DMSO complexes containing coumarin-N-acylhydrazone hybrids: Synthesis, X-ray structures, cytotoxicity and antimicrobial activities

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Cited by 19 publications
(12 citation statements)
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“…HL exhibited irreversible anodic (Ia*) and cathodic (Ic*) processes at –0.196 V and –1.82 V vs. Fc/Fc + , respectively, which were found within similar ranges reported for related compounds , . In the literature, reduction processes exhibited by coumarin and 1,3‐diketone compounds are frequently assigned to carbonyl reduction, which in our case would refer to lactone or β‐keto ester sub‐units.…”
Section: Resultssupporting
confidence: 83%
“…HL exhibited irreversible anodic (Ia*) and cathodic (Ic*) processes at –0.196 V and –1.82 V vs. Fc/Fc + , respectively, which were found within similar ranges reported for related compounds , . In the literature, reduction processes exhibited by coumarin and 1,3‐diketone compounds are frequently assigned to carbonyl reduction, which in our case would refer to lactone or β‐keto ester sub‐units.…”
Section: Resultssupporting
confidence: 83%
“…28 However, it is worth mentioning that the compound with a more lipophilic nature is suitable for bio-imaging studies as the lipophilicity of the probes helps to penetrate the cell membrane. The identity of 1 and 2 was confirmed by 1 H and 13 C NMR, 29 FT-IR, ESI-MS, and elemental analyses (Fig. S1–S8†).…”
Section: Resultsmentioning
confidence: 81%
“…In contrast to other complexes, in complex 3 , the carbonyl (CO) stretching band is retained and it appears at lower frequencies (1620 cm −1 ), and there is an absence of a new CN bond, suggesting that the aroylhydrazone is linked to the metal centre in its neutral form. 58 However, the vibrational band resulting from azomethine stretching vibrations is shifted to a lower wavenumber supporting coordination via azomethine nitrogen. The nitrato complex ( 2 and 4 ) displays two distinct spectral bands in the region of 1355–1455 cm −1 and 1270–1285 cm −1 .…”
Section: Resultsmentioning
confidence: 98%