New Polymorphs of Magnesium‐Based Metal–Organic Frameworks Mg₃(ndc)₃ (ndc = 2,6‐Naphthalenedicarboxylate)

Abstract

Two new magnesium 2,6-naphthalenedicarboxylate (ndc) metal-organic frameworks, [Mg 3 (ndc)

A Family of Chiral Metal–Organic Frameworks

“…Compound 7 crystallizes in the tetragonal, chiral space group P4 3 2 1 2 ( Figure 1d). Trinuclear M 3 A C H T U N G T R E N N U N G (RCO 2 ) 6 (M = Zn, Mg) clusters, a common secondary building unit (SBU) in porous MOFs such as MOF-3 and TUDMOF-2 and -3 [19] form the nodes of the network. The three zinc atoms of the SBU form a nearly linear array (Zn-Zn-Zn-angle 175.8(3)8; Figure 1b).…”

A High Heat of Adsorption for Hydrogen in Magnesium Formate

“…Dybtsev et al [10] observed hydrogen uptake but no nitrogen adsorption in Mn-formate, which is isostruc- tural to the Mg-formate reported in this work. For magnesiumbased frameworks with larger pores Senkovska et al [11,12] observed nitrogen uptake as expected for microporous materials.…”

Microwave synthesis and single-crystal-to-single-crystal transformation of magnesium coordination polymers exhibiting selective gas adsorption and luminescence properties

“…As known, the syntheses of magnesium coordination polymers is still scarce. 8d, [14][15][16][17][18][19][20][21][22][23][24] In this work, we present the microwave synthesis, single-crystal-tosingle-crystal transformation, structural characterization, and multi-functionality for a series of new magnesium coordination polymers including [ (1a). The crystalline solids of 1 to 3 were prepared from the microwave reactions of magnesium(II) nitrate with H 4 BTEC under optimized ratios and different pH value controlled at different basic conditions.…”