1966
DOI: 10.1021/jo01339a018
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New Friedel—Crafts Chemistry. XVI.1 A Reconsideration of Cyclialkylation and Competing Reactions of Certain Phenylalkyl, Benzoylalkyl, and Acetylphenylalkyl Chlorides

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Cited by 16 publications
(11 citation statements)
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“…(2), unidentified ( 18 15 (19), 24 (tr), cis-16 (11), irans-16 (70) 15 (19), 24 (tr), cis-16 (11), trans-16 (70) 15 (20), 24 (tr), cis-16 (9), trans-16 (71) Aids, petroleum ether' 10 20 57…”
Section: Resultsmentioning
confidence: 99%
“…(2), unidentified ( 18 15 (19), 24 (tr), cis-16 (11), irans-16 (70) 15 (19), 24 (tr), cis-16 (11), trans-16 (70) 15 (20), 24 (tr), cis-16 (9), trans-16 (71) Aids, petroleum ether' 10 20 57…”
Section: Resultsmentioning
confidence: 99%
“…The phenylalkyl chlorides required were prethese reactions so that Khalaf and Roberts have pared by decomposition of the chlorosulfite 1 reclassified the field as "new Friedel-Crafts esters of the alcohols or by the action of zinc I chemistry" (2). chloride -hydrochloric acid on the alcohols.…”
Section: Discussion Of Results Identification Have Changed Previous Vmentioning
confidence: 99%
“…5) and ref. 2. The formation of naphthalene is indicative of a hydride transfer mechanism similar to that for cyclialkylation of 1 (Scheme 1).…”
Section: L-dimethyltetralin(93)mentioning
confidence: 90%
“…Under the same reaction conditions, the minor regioisomeric pyrazolines 4 led quantitatively to a mixture of two rearrangement products: 1,3-diphenyl-5-[1-(3-phenylidenyl)methyl]pyrazoles 6 (70%) and 1,3,4-triaryl-4,9-dihydro-10H-4,9-methanobenzo [4,5]cyclohepta[1,2-c]pyrazoles 7 (30%). These structures (Scheme 3) have been established on the basis of their spectroscopic data and an X-ray study of 7c (Ar ϭ p-anisyl).…”
Section: Transformation Of Condensed Pyrazolinesmentioning
confidence: 97%
“…Molecular structure of compound 5b (Ar ϭ p-tolyl) in the crystal trophilic substitution on the neighbouring phenyl group. [3,4] The DQF-COSY [5,6] NMR spectrum of 5d ( Figure 2, Ar ϭ p-nitrophenyl) allowed us to identify each proton. This assignment has been generalised to all compounds 5.…”
Section: Scheme 2 Transformation Of Condensed Pyrazolinesmentioning
confidence: 99%