1968
DOI: 10.1139/v68-549
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Friedel–Crafts rearrangements. IV. Cyclialkylations and hydride transfers on phenylalkyl chlorides

Abstract: A number of phenylalkyl chlorides werc synthesized for a comparative study of Friedel-Crafts cyclialkylations and competing reactions involving hydride exchange. Thc synthetic work showed that phenylbutyl alcohols, especially a tertiary alcohol, may cyclize directly with chlorinating agents to yleld tetralins. Cyclialkylation prod~~cts from phenylpcntyl chloridc include I-methyltetralin (4), 11-pentylbenzene, 1-methyl-3,4-dihydronaphthalene, and methylnaphthalene. A reaction sequence is given involving dealkyl… Show more

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