New Example of Metal‐Containing Monomers for Frontal Polymerization

Abstract

In the present work, new metal‐containing monomers based on copper(II) cinnamate (cinn), viz.: [Cu(cinn)2(bpy)(C2H5OH)], [Cu(cinn)2(phen)(H2O)2], and [Cu(cinn)2(tpy)(C2H5OH)2] (bpy = 2,2′‐bipyridine, phen=1,10‐phenanthroline and tpy=4′‐phenyl‐2,2′:6′,2′′‐terpyridine) were synthesized. At the first time, it was shown that these metal‐containing monomers undergo frontal polymerization.

Preparation of Copper‐containing Nanocomposites by Thermolysis of Copper (II) Complex and Their Use as Anti‐friction and Anti‐wear Additives to Lubricant Oils

“…We have previously shown [28][29][30][31][32][33][34][35] that the nature of the precursor has a significant impact on the main characteristics of the resulting nanomaterials. In particular, the introduction of long-chain hydrocarbon radicals into precursor molecules helps stabilize NPs and prevents their aggregation.…”

Radical-induced cationic frontal polymerisation for prepreg technology

“…Frontal polymerisation is a fast and energy-efficient process in which a localised polymerisation zone is initiated and moves through the whole monomer formulation [21][22][23][24][25][26][27]. Recently, a process called radical-induced cationic frontal polymerisation (RICFP) has been developed for bubble-free bulk curing of epoxy resins [28][29][30][31][32].…”

FeCo@N‐Doped Nanoparticles Encapsulated in Polyacrylamide‐Derived Carbon Nanocages as a Functional Filler for Polyethylene System

“…Recently, nitrogen-metal-carbon (NMC) NPs obtained by thermolysis of precursors containing these elements have received wide attention due to their natural content, economic attractiveness and extended functionality. [23][24][25][26][27][28][29] Previous studies have shown that the activity of NÀ MÀ C catalysts largely correlates with the properties of precursors, thermolysis conditions, type of carbon, content of elements, etc. [30] Recently, Zhou et al synthesized an Fe/N co-doped graphitic carbon bulb with a high nitrogen content by pyrolysis of a Prussian blue precursor at a low temperature of 550°C.…”