New aspects of thallation

Deacon, Glen B.; SMITH, R. N. M.; Tunaley, D.

doi:10.1016/s0022-328x(00)87354-4

Search citation statements

Order By: Relevance

Paper Sections

Select...

Li2psiph31

Citation Types

Supporting

Mentioning

Contrasting

Year Published

1976

2001

Publication Types

Select...

Article5

Other1

Relationship

Self Cite0

Independent6

Authors

Journals

Cited by 11 publications

(1 citation statement)

References 12 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Thallation at -25 °C over 15 min and subsequent quench resulted in the formation of monoiodoanisole (75%; ortho/meta/para = 7:0:93). 211 Obviously, the initially formed para isomer rearranges to the IC stabilized ortho isomer (444; Scheme The gallium center is coordinated in a distorted tetrahedral fashion, with a small O-Ga-C angle (96.7°) due to the formation of a six-membered chelate ring. The IC bond between oxygen and gallium (2.038 A) is the first of its kind.…”

Section: Li2psiph3mentioning

confidence: 99%