Appendix A-Phosphate fibre splicing Appendix B-List of publications during PhD XI LIST OF ACRONYMS AC alternated current BO bridging oxygen CW continuous wave DC direct current DC double cladding DSC differential scanning calorimetry DTA differential thermal analysis EM electromagnetic ESA excited state absorption FWHM full width half maximum GUI graphical user interface IR infrared LASER light amplification by stimulated emission process of radiation LDVT linear variable displacement transducer LED light emitting diode LIDAR light detection and ranging MCVD modified chemical vapour deposition MM multimode NA numerical aperture NIR near infrared NBO non-bridging oxygen OC output coupler OSA optical spectrum analyser OVD Outside vapour deposition PI power-current PCF photonic crystal fibre PCVD Plasma chemical vapour deposition PECVD plasma-enhanced chemical vapour deposition RE rare-earth XII RF radio frequency SBS stimulated Brillouin scattering SESAM saturable absorber mirrors SM single mode SPL solar pumped laser XRD X-ray diffraction TIR total internal reflection UV ultraviolet VAD Vapour phase axial deposition VIS visible brightness, excellent mode quality, high efficiency and enhanced heat dissipation [1,2]. Moreover, fibre laser technology is extremely versatile and could be customized to suit the different applications in terms of output power, operating wavelength, mode of operation (continuous wave CW or pulsed regime), beam quality and dimension, spectral properties and output stability. Therefore fibre lasers find applications in a variety of fields such as industrial material processing, marking, semiconductor device manufacturing, surgery, military technology, remote sensing and scientific instrumentation. Figure I.2. All lasers < 1kW used for Micro Materials Processing [3]. Figure I.3. All lasers ≥1kW used for Macro Materials Processing [3]. Recently there has been a strong interest on the Nd ion emission around 0.9 µm. The main applications are the pumping of Yb and Er doped fibre amplifiers and the generation of blue light obtainable by frequency doubling [12]. This wavelength range has numerous potential applications such as biological and medical diagnostic, trace gas detection and Raman spectroscopy. UV light generation, which can be obtained by devices [23]. In fact the length of the phosphate fibre laser can be substantially decreased even below ten centimetres in order to have an output power in the order of watt level, in a single frequency operation. Moreover, phosphate glasses offer a higher photo-darkening threshold than silica and low nonlinear refractive index, that make them suitable for the realization of high power, high brilliance single-frequency laser sources [24,25]. Another important feature of phosphate glasses is their thermal and This dissertation is organized as follows. Chapter 1 briefly reviews glass definition and main structural and thermodynamics properties. Phosphate glass is introduced along with its peculiar features that made it the material of choice for the deve...