and poor durability of the devices. [1][2][3] The ultrathin fi lm of solid lubricants, which can reduce the friction and extend the life of the underlying surface, shows immense potential for M/NEMS applications. Graphene, a 2D honeycomb lattice of sp 2 hybrid carbons, has attracted a large amount of interest for fundamental studies to application perspective because of its remarkable electronic, optical, thermal, and mechanical properties. [4][5][6] Recently, graphene has been established as an ultrathin solid lubricant exhibiting notable friction-reducing and antiwear properties. [ 7,8 ] The nano-and microscale tribological properties of single/few-layer graphene on solid substrates and chemically derived graphene nanosheets as an additive to liquid lubricants revealed the potential of graphene for lubricant applications. [7][8][9][10][11][12][13] Friction force microscopy and simulation studies demonstrated that friction, adhesion and wear characteristics are controlled by the adhesion between the graphene and the underlying substrate, the interaction between the atomic force microscope (AFM) tip and the graphene, the roughness and presence of wrinkles/folds in the graphene, the number of lamellae in the graphene thin fi lm, the sliding behavior/ direction, the morphology and mechanical properties of the underlying substrate, and the presence of defects and chemical functionalities in the graphene thin fi lm, etc. [ 7,[14][15][16][17][18][19][20][21] The ultrasmooth morphology of graphene and underlying substrate is very crucial to achieving conformal contact for low friction. [ 14 ] Sumant and co-workers demonstrated the wear-resistivity of graphene for a steel tribo-pair under hydrogen atmosphere. At a contact pressure of ≈0.5 GPa, a single layer of graphene showed wear-resistivity for 6400 cycles, while few-layer graphene could last for 47 000 cycles under the hydrogen atmosphere. The extraordinary antiwear properties of graphene was attributed to the stabilization of dangling bonds in the ruptured graphene by hydrogen. [ 22 ] Considering the remarkable friction-reducing and antiwear properties, graphene can be a long-lasting solution to M/ NEMS applications. However, the deposition of graphene thin fi lm on the silicon substrate by epitaxial growth, chemical
Few-layer graphene oxide (GO) is assembled on the silicon surface by a self-assembly approach via covalent interaction using 3-aminopropyltrimethoxysilane (APTMS) as a bifunctional chemical linker. X-ray photoelectron spectroscopy results suggest chemical interactions between oxygen functionalities of GO and amino group ofAPTMS thin fi lm. The oxygen functionalities of GO thin fi lm are eliminated by vacuum ultraviolet (VUV) photon exposure. Topographic images reveal effi cient grafting of GO on the silicon and suggest the presence of few layers in the GO thin fi lm along with wrinkles and folds. Microtribological properties of VUV-reduced GO (rGO) thin fi lm are probed under the mean contact pressure of 0.3-0.6 GPa. The rGO thin fi lm exhibits low and...