“… 2 , 3 Several transition metal dichalcogenides (TMDs) have promptly emerged as possible substitutes or complements to graphene 4 and have already been investigated and proposed for several applications. 5 − 13 More recently, the search for new types of 2D materials has led to the investigation of binary compounds of IV and V groups. Indeed, theoretical calculations have indicated that MX compounds, with M = Si, Ge, Sn, or Pb and X = P, As, Sb, or Bi, might have crystalline layered structures with orthorhombic ( Cmc 2 1 for SiP and Pbam for SiP 2 and GeAs 2 ) or monoclinic ( C 2/ m for GeP, GeAs, and SiAs) symmetries.…”