Nanopolyaniline Coupled with an Anticorrosive Graphene as a 3D Film Electrocatalyst for Efficient Oxidation of Toluene Methyl C−H Bonds and Hydrogen Production at Low Voltage

Abstract

A graphene‐wrapped polyaniline nanoparticles film embedded in carbon cloth (CC/PANI/G) was fabricated and used as a 3D anodic electrocatalyst for oxidation of toluene methyl C−H groups. The methyl C−H bonds can be oxidized effectively at the CC/PANI/G anode with 99.9 % toluene conversion at a low applied voltage of only 1.0 V, which implies low energy input. Importantly, 86.6 % of toluene methyl C−H groups were converted to benzoyl groups (C=O), and hydrogen was produced efficiently at the cathode. The electrocatalytic efficiency at the CC/PANI/G anode was higher at lower voltage (1.0 V) than at higher voltage (1.5 V), and more hydrogen was produced at the corresponding cathode. The synergistic effect between the dynamic redox chemistry of nanoPANI and the excellent conductivity and anticorrosive action of graphene determined the high electrocatalytic efficiency of the oxidation of toluene methyl C−H groups at the CC/PANI/G anode. Owing to the chemical bonding between graphene and PANI, the anticorrosive CC/PANI/G anodic electrocatalyst was durable and effective for oxidation of toluene methyl C−H groups in acidic environment. This approach provides advanced electrode materials for transforming stable chemical bonds (C−H) into useful functional groups (C=O), which will be beneficial for the synthesis of organic intermediates with coupled hydrogen production.

Electrochemical Hydrogen Generation by Oxygen Evolution Reaction‐Alternative Anodic Oxidation Reactions

“…[ 93 ] Mn 3 O 4 NP electrocatalysts were synthesized for epoxidation of cyclooctene and the Mn 3 O 4 NPs(+)||Pt/C(‐) electrolyzer achieved >30% FE toward epoxidation at the anode and >94 ± 5% FE for H 2 generation at the cathode. [ 94 ] Moreover, electrocatalytic oxidation of aloe extract, [ 95 ] toluene methyl CH, [ 96 ] and a variety of aryl, heteroaryl, and alkyl sulfides [ 97 ] were also investigated to support H 2 generation.…”