2002
DOI: 10.1002/1616-3028(20020916)12:9<611::aid-adfm611>3.0.co;2-3
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Abstract: A photoresponsive polymeric hydrogel cantilever that deflects under illumination has been fabricated by using two‐photon three‐dimensional lithography. The hydrogel was prepared from a comonomer solution containing acryloylacetone, acrylamide, and N,N′‐methylene bisacrylamide. The photoresponse of the cantilever was activated by photoexcitation of acetylacetone groups at 244 nm. Deflection of the cantilever by ∼ 45° was effected upon UV irradiation for 20 min.

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Cited by 140 publications
(62 citation statements)
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“…MPP was first developed by Strickler and Webb, [62] and has now been used to create a range of high-resolution 3D free-form structures, including microchannels, [63][64][65] cantilevers, [66][67][68] microgears, [69,70] sub-micrometer oscillators, [71] hydrophobic atomic force microscopy tips, [72] and PhCs. [59,67,[73][74][75][76][77][78][79][80][81] Briefly, MPP utilizes the nonlinear nature of the multiphoton excitation process to only excite dye molecules in a very small volume around the focal point, with dimensions on the order of the resolution limit.…”
Section: Direct Writingmentioning
confidence: 43%
“…MPP was first developed by Strickler and Webb, [62] and has now been used to create a range of high-resolution 3D free-form structures, including microchannels, [63][64][65] cantilevers, [66][67][68] microgears, [69,70] sub-micrometer oscillators, [71] hydrophobic atomic force microscopy tips, [72] and PhCs. [59,67,[73][74][75][76][77][78][79][80][81] Briefly, MPP utilizes the nonlinear nature of the multiphoton excitation process to only excite dye molecules in a very small volume around the focal point, with dimensions on the order of the resolution limit.…”
Section: Direct Writingmentioning
confidence: 43%
“…Actuating structures that have been made from responsive hydrogel are Submitted to 2 either low aspect ratio and their motion is not patternable, [11] or the movement is irreversible. [12] Microscale actuation systems which exhibit reversible chemo-mechanical response and control of actuation direction or pattern have proven difficult to achieve.…”
mentioning
confidence: 43%
“…Researchers have taken various approaches to fabricating biomimetic actuators, among which are biomorph actuators made using Micro Electromechanical Systems (MEMS) technology, [9] magnetically actuated poly(dimethylsiloxane) (PDMS) structures, [10] and artificial cilia or actuators made from responsive gel. [11,12] However, most fabricated actuators, such as MEMS or magneticallyactuated PDMS posts, must be driven by an external force or field and are not responsive to chemical stimuli. Actuating structures that have been made from responsive hydrogel are Submitted to 2 either low aspect ratio and their motion is not patternable, [11] or the movement is irreversible.…”
mentioning
confidence: 44%
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“…We selected readily 35 available acrylic monomer Bisphenol A ethoxylate diacrylate (BPA-EDA) with three different photo- deposition [6], LIGA (X-ray-lithography, electro-forming and mold-56 ing) [7], focused-ion-beam [8,9] and laser holographic lithography 57 [10]. While these techniques allows for fabrication of 3D struc- Direct laser writing (DLW) based two-photon polymerization 63 [11], being a true 3D maskless lithography, with reproducible even 64 sub 100 nm resolution [12], has then recently gained increasing 65 attention in areas such as optics, biology and electronics [13][14][15][16][17][18][19][20]. the cost for the Ti:sapphire system is relatively high, so there's an 87 increasing request for materials that could adapt to the emerging 88 technology of the less expensive femtosecond fiber lasers [23,24] 89 that have the constraint of working at a fixed NIR wavelength (usu-90 ally 780 nm).…”
mentioning
confidence: 44%