Fourier-transform
infrared (FTIR) spectroscopy has been widely applied in oil geochemical
studies, particularly with respect to the physical properties and
maturity of hydrocarbons. However, in general, it has been seldom
used to investigate the organic matter (OM) depositional environment
and source of oil. In this paper, we present such an FTIR spectroscopy
study based on a case investigation in the early Permian alkaline–lacustrine-derived
oils from the Mahu sag, Junggar Basin, Northwest China. The results
define 13 FTIR structural parameters that are associated with the
OM depositional environment, source, and maturity of oil based on
a comparison with well-established oil carbon isotopic and biomarker
data. These would be general to the alkaline (saline)–lacustrine
petroleum systems worldwide. Further combined FTIR spectroscopy and
biomarker parameters in the study area reveal that the lower Permian
Fengcheng formation-derived oils in the Mahu sag were generated from
source rocks deposited in alkaline–saline to brackish–freshwater
environments. The oils have a zoned occurrence, reflecting the general
rules of hydrocarbon generation in alkaline lacustrine environments.
This study represents the first FTIR spectroscopy study of alkaline–lacustrine
oils and suggests that FTIR spectroscopy appears to have considerable
potential in advancing oil geochemical research. The data demonstrate
potential for guiding regional oil exploration.