A key property of photonic crystals is the existence of energy pseudogaps that arise owing to multiple scattering of photons by lattices with periodically varying refractive indices. For certain photonic structures, pseudogaps merge into a complete band gap in three dimensions leading to the localization of light in a cavity mode. [15,16] In the case of disordered structures, [17] one of the most intriguing properties is the effect of Anderson localization of light, [18] the phenomenon that has been observed in a variety of structures of different dimensions. [19] Historically, the study of Anderson localization has focused on disordered substances, although the possibility of observing localization in perfect quasicrystals has also been discussed. However, the effect was observed only in 2D quasicrystalline structures in the presence of strong disorder [8] or under the action of nonlinearity. [20] Nevertheless, the existence of a clearly defined photonic band structure in 3D icosahedral quasicrystals, [21] the observation of Bragg diffraction, [22] the multiple scattering of light within the structure, [23] and laser generation from dye-doped samples [24] were promising signs for the possibility of an experimental observation of intrinsic light localization in defect-free 3D quasicrystals Figure 1. Additional evidence is a recent report in which intrinsic localization was theoretically predicted in icosahedral quasicrystals. [10] Although the Ioffe-Regel criterion [25] for localization in disordered materials (the wavelength λ becomes comparable to the transport mean free path l * , that is kl * ≤ 1, where k = 2π/λ is the wave vector) is not fulfilled in icosahedral quasicrystals, the authors argued that band flattening at high frequencies of the calculated photonic band structure corresponds to a slower group velocity and a decrease in the scattering mean free path which increases the possibility of wave localization in terms of the Ioffe-Regel condition. [10] Here, to the best of our knowledge, we present the first experimental observation of intrinsic light localization in defect-free 3D quasicrystalline material. In addition, we studied Bragg diffraction in the visible region on the same samples uncovering their regular structure. Sample Fabrication: To fabricate experimental samples, a computer model of an icosahedral quasicrystalline structure was generated first in accordance with the substitution rules. [10] These quasicrystals had icosahedral symmetry with 15 C 2v , 10 C 3v , and 6 C 5v axes, [21] which led to the absence of periodicity, despite the fact that the structures had perfect ordering and regularity. The samples herein consisted of six radial layers