Multiferroics

Abstract

This special issue deals with the simultaneous occurrence of at least two primary ferroic properties, namely of ferroelectricity, ferromagnetism, ferrotoroidicity or ferroelasticity in one single homogeneous phase. The question of how different ferroic states can coexist in a single-phase material is an important issue and is outlined in detail using symmetry arguments and Landau theory for continuous phase transitions, which shows that the spin structure alone can break spatial inversion symmetry leading to ferroelectric order. The main focus of this special issue lies on single-phase materials that are magnetic and ferroelectric. They promise control of electric properties by magnetic fields and the control of magnetic properties by electric fields. The magnetoelectric coupling will allow the design of materials with novel electronic properties and in selected cases bring them to application.Ferromagnetic ferroelectrics are scarce in nature. This is because the conventional mechanism for ferroelectricity, namely an off-centering of the cations, which can be achieved best in ions with empty d shells, contradicts the formation of magnetic order in materials with partly filled d shells [1,2]. Ferroelectricity in specific cases is achieved via the stereochemical activity of lone pairs in magnetic oxides. But in these cases the coupling between ferroelectricty and magnetism is weak. There have been a number of studies on multiferroics, especially in the 1960s and 1970s, particularly in the former Soviet Union [3,4], but these activities faded away, most probably due to the lack of materials with strong magnetoelectric coupling and high ordering temperature, although the enormous potential of multiferroics for technological important applications was recognized early on [5].An intense revival and the return of multiferroicity to the forefront of condensed matter research has been triggered by the invention of a number of frustrated magnets, like manganite rare earths, i.e., RMnO 3 [6], RMn 2 O 5 [7], or Ni 3 V 2 O 8 [8], which are characterized by strong spin frustration due to competing exchange interactions. In fact, they reveal transitions into magnetic phases with complex non-collinear spin order, thereby breaking inversion symmetry and concomitantly inducing ferroelectricity. This renaissance of multiferroics was made possible because developments in sample growth and sample characterization allowed the production of high quality single crystals and thin films. In addition, computational methods helped to design new materials with outstanding properties.To explore the complex physics of multiferroics, outstanding laboratories with novel instrumentation and exceptional theoretical tools were involved. Most of the scientists responsible for this enormous revival in the synthesis, characterization, and modeling of these new classes of multiferroics have contributed to this special issue. Hence, it provides an impressive survey of the state of the art and documents key experiments in this area of condensed matter re...

Multiferroic Behavior of Gd Based Manganite

“…The study of ferroelectricity and magnetism has led to some of the most important technological advances [1][2][3][4]. Magnetism and ferroelectricity are involved with local spins and off-center structural distortions, respectively.…”

EXAFS, XANES, and DFT study of the mixed-valence compoundYMn2O5: Site-selective substitution of Fe for Mn

“…9 Another interesting series of mixed-valence manganites with the DyMn 2 O 5 type of structure, orthorhombic RMn 2 O 5 , is in the focus of current research due to the occurrence of antiferromagnetic ordering as well as ferroelectric phase transitions at low temperatures. A significant magnetoferroelectric effect, implying a coupling between ferroelectricity and magnetic ordering, has been observed 7,[14][15][16][17][18][19][20][21][22] and is typical for these substances. 23 This suggests the possibility to control the electric polarization by an external magnetic field giving rise to parts of the above-mentioned applications.…”

Insight into the Growth Reaction Mechanism of Ceramic Co3TeO6: Synchrotron Structural and Thermal Analysis

“…M ULTIFERROICS, wherein coupling among various ferroicorder parameters like electrical polarization (P) and magnetization (M) in the same phase occurs, have attracted great attentions due to their promising application in spintronics, magnetic data storage devices, solar cell, etc. [1][2][3][4] In the quest of the new and better performing materials, cobalt tellurate Co 3 TeO 6 (CTO) seems to have favorable characteristics. [5][6][7][8] The renewed interest in CTO is due to its low-temperature type II multiferroic property.…”