Multi-analytical approach and microstructural characterisation of glasses from the Celtic oppidum of Třísov, Czech Republic, second to first centuries BC
“…The lack of glassmaking structures, such as kilns, and associated tools or production waste point to the fact that raw glass was imported from the Mediterranean and shaped into products that were adapted to express a common identity/aesthetic among La Tène populations. Glass used in the production of Celtic artefacts has uniformly been found to contain high Na 2 O and low K 2 O and MgO content, consistent with natron-fluxed glass [7,27,[99][100][101][102]. Other Mediterranean goods, such as wine, as attested by imports of amphorae, were also part of Celtic-Mediterranean trade [100].…”
Section: Celtic Glass and The Mediterranean Glass Monopoly (3rd-1st C...mentioning
confidence: 99%
“…It is definitely interesting to note that only the natron-fluxed glass from the western Mediterranean exhibits unusually high alumina contents [94,95]. It still remains to be seen if this could signify the existence of a Western glass supply chain, because data for Iron Age vitreous materials from the Iberian Peninsula and the islands are overall limited [40,41,[94][95][96][97][98][99][100][101][102][103][104][105][106][107][108][109][110][111][112]. Beads with a high Al 2 O 3 content (3.42-14.41 wt.…”
Section: The Turning Point In Natron Glass Production (Ca 6th Century...mentioning
confidence: 99%
“…Proposed routes likely followed major rivers to facilitate transportation. Like for Hellenistic core-formed vessels, Sr/Zr ratios show a division of Celtic glass into Egyptian and Levantine groups [7,25,27,58,59,99,100,102]. High-Zr Egyptian glass was found to be more common among earlier Celtic glass dated to the Lt C1 phase [59,99].…”
Section: Celtic Glass and The Mediterranean Glass Monopoly (3rd-1st C...mentioning
confidence: 99%
“…High-Zr Egyptian glass was found to be more common among earlier Celtic glass dated to the Lt C1 phase [59,99]. The transition to high-Sr Levantine glass occurred during the late Lt C2 phase, around the early 2nd century BCE, and is typical of the late La Tène period (early 2nd-late 1st century BCE) [59,99,102]. This chrono-compositional picture is directly opposite from that noticed for Hellenistic core-formed vessels, where Egyptian compositions feature in chronologically younger Groups II and III [56], which raises the question of what, if further data on Mediterranean Group III vessels do not dispute it, caused this reversal to occur.…”
Section: Celtic Glass and The Mediterranean Glass Monopoly (3rd-1st C...mentioning
Ancient glass has been extensively studied from a technological and raw material provenance perspective since the middle of the 20th century. With the rising applications of analytical techniques in the field of Heritage Studies, the last two decades saw an exponential increase in publications on ancient and historical glass technology from around the globe. Given the amount of works on glass chemical composition, it is surprising to note that the long-held production model for Iron Age glasses found in Europe has only recently been challenged by the publication of uncharacteristic glass compositions. Traditionally, LBA glass industries based on plant-ash fluxes/HMG (Egypt and the Levant) and mixed-alkali fluxes/LMHK (Italy) are thought to be supplanted by natron-fluxed/LMG production operating in Egypt and the Levant since around the 9th century BCE. Recently, however, arguments have been put forth for a more diversified network of glassmaking traditions, including small-scale autonomous European workshops. This article reviews the current state of research into Iron Age (1st millennium BCE) glasses in Europe by examining the available published data on glass compositions to critically assess some practical and theoretical issues stemming from this heterogenous field of research. Key questions are addressed, and future lanes of research are proposed.
“…The lack of glassmaking structures, such as kilns, and associated tools or production waste point to the fact that raw glass was imported from the Mediterranean and shaped into products that were adapted to express a common identity/aesthetic among La Tène populations. Glass used in the production of Celtic artefacts has uniformly been found to contain high Na 2 O and low K 2 O and MgO content, consistent with natron-fluxed glass [7,27,[99][100][101][102]. Other Mediterranean goods, such as wine, as attested by imports of amphorae, were also part of Celtic-Mediterranean trade [100].…”
Section: Celtic Glass and The Mediterranean Glass Monopoly (3rd-1st C...mentioning
confidence: 99%
“…It is definitely interesting to note that only the natron-fluxed glass from the western Mediterranean exhibits unusually high alumina contents [94,95]. It still remains to be seen if this could signify the existence of a Western glass supply chain, because data for Iron Age vitreous materials from the Iberian Peninsula and the islands are overall limited [40,41,[94][95][96][97][98][99][100][101][102][103][104][105][106][107][108][109][110][111][112]. Beads with a high Al 2 O 3 content (3.42-14.41 wt.…”
Section: The Turning Point In Natron Glass Production (Ca 6th Century...mentioning
confidence: 99%
“…Proposed routes likely followed major rivers to facilitate transportation. Like for Hellenistic core-formed vessels, Sr/Zr ratios show a division of Celtic glass into Egyptian and Levantine groups [7,25,27,58,59,99,100,102]. High-Zr Egyptian glass was found to be more common among earlier Celtic glass dated to the Lt C1 phase [59,99].…”
Section: Celtic Glass and The Mediterranean Glass Monopoly (3rd-1st C...mentioning
confidence: 99%
“…High-Zr Egyptian glass was found to be more common among earlier Celtic glass dated to the Lt C1 phase [59,99]. The transition to high-Sr Levantine glass occurred during the late Lt C2 phase, around the early 2nd century BCE, and is typical of the late La Tène period (early 2nd-late 1st century BCE) [59,99,102]. This chrono-compositional picture is directly opposite from that noticed for Hellenistic core-formed vessels, where Egyptian compositions feature in chronologically younger Groups II and III [56], which raises the question of what, if further data on Mediterranean Group III vessels do not dispute it, caused this reversal to occur.…”
Section: Celtic Glass and The Mediterranean Glass Monopoly (3rd-1st C...mentioning
Ancient glass has been extensively studied from a technological and raw material provenance perspective since the middle of the 20th century. With the rising applications of analytical techniques in the field of Heritage Studies, the last two decades saw an exponential increase in publications on ancient and historical glass technology from around the globe. Given the amount of works on glass chemical composition, it is surprising to note that the long-held production model for Iron Age glasses found in Europe has only recently been challenged by the publication of uncharacteristic glass compositions. Traditionally, LBA glass industries based on plant-ash fluxes/HMG (Egypt and the Levant) and mixed-alkali fluxes/LMHK (Italy) are thought to be supplanted by natron-fluxed/LMG production operating in Egypt and the Levant since around the 9th century BCE. Recently, however, arguments have been put forth for a more diversified network of glassmaking traditions, including small-scale autonomous European workshops. This article reviews the current state of research into Iron Age (1st millennium BCE) glasses in Europe by examining the available published data on glass compositions to critically assess some practical and theoretical issues stemming from this heterogenous field of research. Key questions are addressed, and future lanes of research are proposed.
“…To demonstrate the usefulness of Ilaps application a range of samples were analysed, such as bulk analysis of archaeological samples, 18,19 imaging of platinum in tumour tissue of a mouse 20 and other biological samples, [21][22][23] geological samples 24,25 or imaging of the corrosion of Ni-based alloy. 26 In addition to Ilaps being used for many transdisciplinary collaborations, it also offers a way to easily handle data from other instruments, such as laser-induced breakdown spectroscopy (LIBS), 27 just by simple conversion of raw data to t the importing format.…”
In the past couple of years, laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) has been widely used for trace element analysis in solid samples and the study of their...
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