Mukaiyama and Torgov Chemistry in the Synthesis of (D‐Homo) Steroid Skeletons

Sarabèr, Florence C.E.; Drach, S. V.; Baranovsky, A. V.; Charnikhova, Tanya; Pogrebnoi, Serghei; Jansen, B. J. M.; Groot, Aede de

doi:10.1002/chin.200628243

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2007

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“…The synthesis of functionalized steroid skeletons in overall yields of about 50% can be achieved in four steps in this way (Scheme 15). 52,53 On the basis of Mukaiyama chemistry, a further efficient procedure has been developed to obtain C,Dcis annelated D-homosteroids. …”

Section: Scheme 14mentioning

confidence: 99%

Recent Developments in the Isolation and Synthesis of D‐Homosteroids and Related Compounds

Wölfling¹

2007

ChemInform

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Both naturally occurring and synthetic D-homologs of compounds with a sterane skeleton exhibit diverse biological activity. The main sources of isolation are plants and marine organisms. The synthetic D-homosteroids are potential leads for drug discovery. This review focuses on steroids with a six-membered carbocyclic ring D and related compounds, the isolation or syntheses of which were reported between the mid-1990s and mid-2006.

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Section: Scheme 14mentioning

confidence: 99%