By in‐situ etching of a ZnO buffer layer freestanding GaN layers were prepared by hydride vapor phase epitaxy (HVPE). For the template growth, single crystalline ZnO buffer layers, grown by pulsed laser deposition on sapphire, were used. They were overgrown with a thin GaN layer by a multilayer growth using metal organic vapor phase epitaxy (MOVPE).
The removal of the ZnO buffer during the HVPE growth allowed the fabrication of strain‐free freestanding GaNlayers with a full width‐half‐maximum of the donor bound exciton (D0X) of 2.3 meV at a position of 3.47 eV in low temperature (15 K) photoluminescence (© 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)