The temporal trends of polychlorinated biphenyls (PCBs), polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) and polybrominated diphenyl ethers (PBDEs) were investigated in soils from an E-waste dismantling area in East China between 2005 and 2011. Isotope dilution high resolution gas chromatography/high resolution mass spectrometry (HRGC/HRMS) was employed for the sample analysis. PCB levels declined as expected, while PCDD/Fs generally remained at a constant level during the sampling period, and PBDE concentrations tended to be slightly lower after 2007 although the decline was not statistically significant. The congener profiles indicated that lowly-halogenated congeners of these persistent organic pollutants (POPs) accounted for the decreasing levels and relative proportions of the POPs, suggesting that they have been gradually eliminated from the field soil over the years. However, the concentration levels of some heavy congeners (e.g., OCDD and OCDF) showed different trends from those of the lighter ones. The general tendencies of the three types of POPs in soils were consistent with those reported in other studies in this area. The results implied that the enhanced regulations and centralized dismantling action introduced in 2005 might exert a limited influence on these three types of POPs in soils during the sampling period.
Environmental impactThe environmental contamination associated with E-waste dismantling activities has been a topic of great concern during the past several decades. In China, two notorious E-waste recycling centers are hot spots for POPs research, which are respectively located in Guiyu, South China and Taizhou, East China. The present study was conducted to investigate the levels and distribution of PCBs, PCDD/Fs and PBDEs in soils from the Taizhou area to reect the temporal tendency of POPs aer stricter environmental regulations were introduced by local government in 2005. The results revealed that different temporal trends occurred for the different POPs, which were closely related to their historical emission and their chemical properties. The study will shed light on the contamination control for these POPs in E-waste dismantling areas.