“…Therefore, the exploitation for novel and replaceable electrode materials with high properties of Sodium/Lithium-ion batteries is extremely urgent. [8][9][10] In contrast with most transition-metal fluorine (TMF 2 , TM = Co, Ni, Fe, Cu, Zn. ), MnF 2 shows momentous potential owing to its high theoretical capacity of 0.577 Ah/g, low cost, natural abundance, and environmental benign.…”