“…Different forms of active HER MoS 2 electrocatalysts have been developed, including crystalline nanoparticles, amorphous films and molecular clusters [ 1 , 3 , 6 , 17 , 18 , 19 , 20 , 21 , 22 , 23 , 24 , 25 , 26 , 27 ]. MoS 2 is also characterized by unique photocatalytic properties [ 3 , 6 , 28 , 29 , 30 , 31 , 32 , 33 , 34 , 35 , 36 ]. This is due to the fact that S-Mo-S coordination in the crystal lattice generates unsaturated Mo and S atoms at the edges, resulting in highly active sites to perform H 2 production via water splitting [ 3 , 6 , 17 , 28 , 29 , 32 , 37 ].…”