The world is currently facing critical water and energy issues due to the growing population and industrialization, calling for methods to obtain potable water, e.g., by photocatalysis, and to convert solar energy into fuels such as chemical or electrical energy, then storing this energy. Energy storage has been recently improved by using electrochemical capacitors and ion batteries. Research is actually focusing on the synthesis of materials and hybrids displaying improved electronic, physiochemical, electrical, and optical properties. Here, we review molybdenum disulfide (MoS2) materials and hybrids with focus on synthesis, electronic structure and properties, calculations of state, bandgap and charge density profiles, and applications in energy storage and water remediation.
The rapid urbanization and industrialization is causing worldwide water pollution, calling for advanced cleaning methods. For instance, pollutant adsorption on magnetic oxides is efficient and very practical due to the easy separation from solutions by an magnetic field. Here we review the synthesis and performance of magnetic oxides such as iron oxides, spinel ferrites, and perovskite oxides for water remediation. We present structural, optical, and magnetic properties. Magnetic oxides are also promising photocatalysts for the degradation of organic pollutants. Antimicrobial activities and adsorption of heavy metals and radionucleides are also discussed.
Agriculture and industrial wastes (AIWs) have attracted much attention because of their huge environmental, economic, and social impacts. AIWs have been considered a crucial link of a closed-loop for the fabrication of nanomaterials and composites wherein they replace traditional resources with sustainable waste in waste management. In this context, the proper disposal of AIWs is required. This review aims to investigate the technical feasibility of using innovative AIW resources and various strategies for the fabrication of nanomaterials for improving energy applications. First, the utilization of AIWs is classified comprehensively. Second, key technologies to produce nanomaterials are summarized. In addition, this review discusses the potential applications of the fabricated nanomaterials in energy storage and energy conversion.
Two ethoxylated nonionic
surfactants (L400 and L600) based on Schiff
base are prepared from polyoxyethylene, glyoxalic acid, and phenylenediamine.
They are evaluated electrochemically as carbon steel corrosion inhibitors
in 1 M HCl by electrochemical impedance spectroscopy (EIS) and Tafel
techniques and complemented with microscopic analysis methods. The
obtained Tafel data indicate the mixed-type behavior of the inhibitor
used. The inhibition efficiency touches the peak at 1 × 10
–4
M, exhibiting 92 and 94% for L400 and L600, respectively.
The presence of the tested inhibitors decreases corrosion current
density (
i
corr
) and double-layer capacitance
(
C
dl
) due to the formation of a protective
adsorption layer in place of the already adsorbed water and aggressive
Cl
–
ions. Both L400 and L600 adsorption modes follow
Langmuir adsorption isotherm. The density functional theory (DFT)
calculated indices (Δ
E
gap
and
E
HOMO
) indicate the superiority of L600 over
the L400 counterpart as a reactive compound. Adsorption of L600 and
L400 over the Fe(1 1 0) in simulated acidic medium is
investigated by Monte Carlo (MC) simulation to verify their inhibition
performance and are matched with adsorption free energy Δ
G
ads
calculated values. Both experimental and
theoretical data are in agreement.
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